Formose reaction accelerated in aerosol-OT reverse micelles

The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in th...

Descripción completa

Detalles Bibliográficos
Autores principales: Masaoka, Makoto, Michitaka, Tomohiro, Hashidzume, Akihito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238542/
https://www.ncbi.nlm.nih.gov/pubmed/28144336
http://dx.doi.org/10.3762/bjoc.12.262
_version_ 1782495722154754048
author Masaoka, Makoto
Michitaka, Tomohiro
Hashidzume, Akihito
author_facet Masaoka, Makoto
Michitaka, Tomohiro
Hashidzume, Akihito
author_sort Masaoka, Makoto
collection PubMed
description The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in the formose reaction. The (13)C NMR spectra for the products of the formose reaction using formaldehyde-(13)C as starting material are indicative of the formation of ethylene glycol as a major product.
format Online
Article
Text
id pubmed-5238542
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-52385422017-01-31 Formose reaction accelerated in aerosol-OT reverse micelles Masaoka, Makoto Michitaka, Tomohiro Hashidzume, Akihito Beilstein J Org Chem Letter The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in the formose reaction. The (13)C NMR spectra for the products of the formose reaction using formaldehyde-(13)C as starting material are indicative of the formation of ethylene glycol as a major product. Beilstein-Institut 2016-12-07 /pmc/articles/PMC5238542/ /pubmed/28144336 http://dx.doi.org/10.3762/bjoc.12.262 Text en Copyright © 2016, Masaoka et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Masaoka, Makoto
Michitaka, Tomohiro
Hashidzume, Akihito
Formose reaction accelerated in aerosol-OT reverse micelles
title Formose reaction accelerated in aerosol-OT reverse micelles
title_full Formose reaction accelerated in aerosol-OT reverse micelles
title_fullStr Formose reaction accelerated in aerosol-OT reverse micelles
title_full_unstemmed Formose reaction accelerated in aerosol-OT reverse micelles
title_short Formose reaction accelerated in aerosol-OT reverse micelles
title_sort formose reaction accelerated in aerosol-ot reverse micelles
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238542/
https://www.ncbi.nlm.nih.gov/pubmed/28144336
http://dx.doi.org/10.3762/bjoc.12.262
work_keys_str_mv AT masaokamakoto formosereactionacceleratedinaerosolotreversemicelles
AT michitakatomohiro formosereactionacceleratedinaerosolotreversemicelles
AT hashidzumeakihito formosereactionacceleratedinaerosolotreversemicelles

Ejemplares similares