Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols

A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita–Baylis–Hillman (MBH) alcohols, using Et(3)B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been ob...

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Autores principales: Abidi, Ahlem, Oueslati, Yosra, Rezgui, Farhat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238553/
https://www.ncbi.nlm.nih.gov/pubmed/28144308
http://dx.doi.org/10.3762/bjoc.12.234
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author Abidi, Ahlem
Oueslati, Yosra
Rezgui, Farhat
author_facet Abidi, Ahlem
Oueslati, Yosra
Rezgui, Farhat
author_sort Abidi, Ahlem
collection PubMed
description A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita–Baylis–Hillman (MBH) alcohols, using Et(3)B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity.
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spelling pubmed-52385532017-01-31 Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols Abidi, Ahlem Oueslati, Yosra Rezgui, Farhat Beilstein J Org Chem Full Research Paper A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita–Baylis–Hillman (MBH) alcohols, using Et(3)B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity. Beilstein-Institut 2016-11-15 /pmc/articles/PMC5238553/ /pubmed/28144308 http://dx.doi.org/10.3762/bjoc.12.234 Text en Copyright © 2016, Abidi et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Abidi, Ahlem
Oueslati, Yosra
Rezgui, Farhat
Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
title Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
title_full Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
title_fullStr Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
title_full_unstemmed Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
title_short Et(3)B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita–Baylis–Hillman alcohols
title_sort et(3)b-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with morita–baylis–hillman alcohols
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238553/
https://www.ncbi.nlm.nih.gov/pubmed/28144308
http://dx.doi.org/10.3762/bjoc.12.234
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