Supramolecular frameworks based on [60]fullerene hexakisadducts

[60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the fram...

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Autores principales: Kraft, Andreas, Stangl, Johannes, Krause, Ana-Maria, Müller-Buschbaum, Klaus, Beuerle, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238557/
https://www.ncbi.nlm.nih.gov/pubmed/28179942
http://dx.doi.org/10.3762/bjoc.13.1
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author Kraft, Andreas
Stangl, Johannes
Krause, Ana-Maria
Müller-Buschbaum, Klaus
Beuerle, Florian
author_facet Kraft, Andreas
Stangl, Johannes
Krause, Ana-Maria
Müller-Buschbaum, Klaus
Beuerle, Florian
author_sort Kraft, Andreas
collection PubMed
description [60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and sorption measurements.
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spelling pubmed-52385572017-02-08 Supramolecular frameworks based on [60]fullerene hexakisadducts Kraft, Andreas Stangl, Johannes Krause, Ana-Maria Müller-Buschbaum, Klaus Beuerle, Florian Beilstein J Org Chem Full Research Paper [60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and sorption measurements. Beilstein-Institut 2017-01-02 /pmc/articles/PMC5238557/ /pubmed/28179942 http://dx.doi.org/10.3762/bjoc.13.1 Text en Copyright © 2017, Kraft et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kraft, Andreas
Stangl, Johannes
Krause, Ana-Maria
Müller-Buschbaum, Klaus
Beuerle, Florian
Supramolecular frameworks based on [60]fullerene hexakisadducts
title Supramolecular frameworks based on [60]fullerene hexakisadducts
title_full Supramolecular frameworks based on [60]fullerene hexakisadducts
title_fullStr Supramolecular frameworks based on [60]fullerene hexakisadducts
title_full_unstemmed Supramolecular frameworks based on [60]fullerene hexakisadducts
title_short Supramolecular frameworks based on [60]fullerene hexakisadducts
title_sort supramolecular frameworks based on [60]fullerene hexakisadducts
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238557/
https://www.ncbi.nlm.nih.gov/pubmed/28179942
http://dx.doi.org/10.3762/bjoc.13.1
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