Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia

Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)ami...

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Autores principales: Semakin, Artem N, Kokuev, Aleksandr O, Nelyubina, Yulia V, Sukhorukov, Alexey Yu, Zhmurov, Petr A, Ioffe, Sema L, Tartakovsky, Vladimir A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238579/
https://www.ncbi.nlm.nih.gov/pubmed/28144315
http://dx.doi.org/10.3762/bjoc.12.241
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author Semakin, Artem N
Kokuev, Aleksandr O
Nelyubina, Yulia V
Sukhorukov, Alexey Yu
Zhmurov, Petr A
Ioffe, Sema L
Tartakovsky, Vladimir A
author_facet Semakin, Artem N
Kokuev, Aleksandr O
Nelyubina, Yulia V
Sukhorukov, Alexey Yu
Zhmurov, Petr A
Ioffe, Sema L
Tartakovsky, Vladimir A
author_sort Semakin, Artem N
collection PubMed
description Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated.
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spelling pubmed-52385792017-01-31 Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia Semakin, Artem N Kokuev, Aleksandr O Nelyubina, Yulia V Sukhorukov, Alexey Yu Zhmurov, Petr A Ioffe, Sema L Tartakovsky, Vladimir A Beilstein J Org Chem Full Research Paper Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated. Beilstein-Institut 2016-11-21 /pmc/articles/PMC5238579/ /pubmed/28144315 http://dx.doi.org/10.3762/bjoc.12.241 Text en Copyright © 2016, Semakin et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Semakin, Artem N
Kokuev, Aleksandr O
Nelyubina, Yulia V
Sukhorukov, Alexey Yu
Zhmurov, Petr A
Ioffe, Sema L
Tartakovsky, Vladimir A
Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
title Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
title_full Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
title_fullStr Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
title_full_unstemmed Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
title_short Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
title_sort construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238579/
https://www.ncbi.nlm.nih.gov/pubmed/28144315
http://dx.doi.org/10.3762/bjoc.12.241
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