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Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia

Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)ami...

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Detalles Bibliográficos
Autores principales: Semakin, Artem N, Kokuev, Aleksandr O, Nelyubina, Yulia V, Sukhorukov, Alexey Yu, Zhmurov, Petr A, Ioffe, Sema L, Tartakovsky, Vladimir A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238579/
https://www.ncbi.nlm.nih.gov/pubmed/28144315
http://dx.doi.org/10.3762/bjoc.12.241