Formose reaction controlled by boronic acid compounds

Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided differ...

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Detalles Bibliográficos
Autores principales: Imai, Toru, Michitaka, Tomohiro, Hashidzume, Akihito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238582/
https://www.ncbi.nlm.nih.gov/pubmed/28144337
http://dx.doi.org/10.3762/bjoc.12.263
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author Imai, Toru
Michitaka, Tomohiro
Hashidzume, Akihito
author_facet Imai, Toru
Michitaka, Tomohiro
Hashidzume, Akihito
author_sort Imai, Toru
collection PubMed
description Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided different selectivities; sugars of a small carbon number were formed favorably in the presence of SPB, whereas sugar alcohols of a larger carbon number were formed preferably in the presence of pVPB/NaSS.
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spelling pubmed-52385822017-01-31 Formose reaction controlled by boronic acid compounds Imai, Toru Michitaka, Tomohiro Hashidzume, Akihito Beilstein J Org Chem Letter Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided different selectivities; sugars of a small carbon number were formed favorably in the presence of SPB, whereas sugar alcohols of a larger carbon number were formed preferably in the presence of pVPB/NaSS. Beilstein-Institut 2016-12-08 /pmc/articles/PMC5238582/ /pubmed/28144337 http://dx.doi.org/10.3762/bjoc.12.263 Text en Copyright © 2016, Imai et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Imai, Toru
Michitaka, Tomohiro
Hashidzume, Akihito
Formose reaction controlled by boronic acid compounds
title Formose reaction controlled by boronic acid compounds
title_full Formose reaction controlled by boronic acid compounds
title_fullStr Formose reaction controlled by boronic acid compounds
title_full_unstemmed Formose reaction controlled by boronic acid compounds
title_short Formose reaction controlled by boronic acid compounds
title_sort formose reaction controlled by boronic acid compounds
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238582/
https://www.ncbi.nlm.nih.gov/pubmed/28144337
http://dx.doi.org/10.3762/bjoc.12.263
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AT michitakatomohiro formosereactioncontrolledbyboronicacidcompounds
AT hashidzumeakihito formosereactioncontrolledbyboronicacidcompounds

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