Ordering of Zn-centered porphyrin and phthalocyanine on TiO(2)(011): STM studies

Zn(II)phthalocyanine molecules (ZnPc) were thermally deposited on a rutile TiO(2)(011) surface and on Zn(II)meso-tetraphenylporphyrin (ZnTPP) wetting layers at room temperature and after elevated temperature thermal processing. The molecular homo- and heterostructures were characterized by high-reso...

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Detalles Bibliográficos
Autores principales: Olszowski, Piotr, Zajac, Lukasz, Godlewski, Szymon, Such, Bartosz, Pawlak, Rémy, Hinaut, Antoine, Jöhr, Res, Glatzel, Thilo, Meyer, Ernst, Szymonski, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238625/
https://www.ncbi.nlm.nih.gov/pubmed/28144569
http://dx.doi.org/10.3762/bjnano.8.11
Descripción
Sumario:Zn(II)phthalocyanine molecules (ZnPc) were thermally deposited on a rutile TiO(2)(011) surface and on Zn(II)meso-tetraphenylporphyrin (ZnTPP) wetting layers at room temperature and after elevated temperature thermal processing. The molecular homo- and heterostructures were characterized by high-resolution scanning tunneling microscopy (STM) at room temperature and their geometrical arrangement and degree of ordering are compared with the previously studied copper phthalocyanine (CuPc) and ZnTPP heterostructures. It was found that the central metal atom may play some role in ordering and growth of phthalocyanine/ZnTPP heterostructures, causing differences in stability of upright standing ZnPc versus CuPc molecular chains at given thermal annealing conditions.

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