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TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides

A TBHP-mediated dehydrogenative cross-oxidative-coupling approach has been developed for the synthesis of N-arylbenzamides from methylarenes and acetanilides. This cross-coupling method is free of transition metal catalysts and ligands, and no extra organic solvents are required, which make it an us...

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Detalles Bibliográficos
Autores principales: Chen, Cui, Liu, Weibing, Zhou, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238673/
https://www.ncbi.nlm.nih.gov/pubmed/28144291
http://dx.doi.org/10.3762/bjoc.12.217
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author Chen, Cui
Liu, Weibing
Zhou, Peng
author_facet Chen, Cui
Liu, Weibing
Zhou, Peng
author_sort Chen, Cui
collection PubMed
description A TBHP-mediated dehydrogenative cross-oxidative-coupling approach has been developed for the synthesis of N-arylbenzamides from methylarenes and acetanilides. This cross-coupling method is free of transition metal catalysts and ligands, and no extra organic solvents are required, which make it an useful and attractive strategy for the straightforward construction of C–N bonds. Besides, this conversion is an important complement to the conventional C–N forming strategies.
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spelling pubmed-52386732017-01-31 TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides Chen, Cui Liu, Weibing Zhou, Peng Beilstein J Org Chem Full Research Paper A TBHP-mediated dehydrogenative cross-oxidative-coupling approach has been developed for the synthesis of N-arylbenzamides from methylarenes and acetanilides. This cross-coupling method is free of transition metal catalysts and ligands, and no extra organic solvents are required, which make it an useful and attractive strategy for the straightforward construction of C–N bonds. Besides, this conversion is an important complement to the conventional C–N forming strategies. Beilstein-Institut 2016-10-25 /pmc/articles/PMC5238673/ /pubmed/28144291 http://dx.doi.org/10.3762/bjoc.12.217 Text en Copyright © 2016, Chen et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Chen, Cui
Liu, Weibing
Zhou, Peng
TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
title TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
title_full TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
title_fullStr TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
title_full_unstemmed TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
title_short TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
title_sort tbhp-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238673/
https://www.ncbi.nlm.nih.gov/pubmed/28144291
http://dx.doi.org/10.3762/bjoc.12.217
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