Temperature dependent CO(2) behavior in microporous 1-D channels of a metal-organic framework with multiple interaction sites

The MOF with the encapsulated CO(2) molecule shows that the CO(2) molecule is ligated to the unsaturated Cu(II) sites in the cage using its Lewis basic oxygen atom via an angular η(1)-(O(A)) coordination mode and also interacts with Lewis basic nitrogen atoms of the tetrazole ligands using its Lewis...

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Detalles Bibliográficos
Autores principales: Kim, Dongwook, Park, Jaehun, Kim, Yung Sam, Lah, Myoung Soo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5269755/
https://www.ncbi.nlm.nih.gov/pubmed/28128298
http://dx.doi.org/10.1038/srep41447

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5269755/
https://www.ncbi.nlm.nih.gov/pubmed/28128298
http://dx.doi.org/10.1038/srep41447

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