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Temperature dependent CO(2) behavior in microporous 1-D channels of a metal-organic framework with multiple interaction sites
The MOF with the encapsulated CO(2) molecule shows that the CO(2) molecule is ligated to the unsaturated Cu(II) sites in the cage using its Lewis basic oxygen atom via an angular η(1)-(O(A)) coordination mode and also interacts with Lewis basic nitrogen atoms of the tetrazole ligands using its Lewis...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5269755/ https://www.ncbi.nlm.nih.gov/pubmed/28128298 http://dx.doi.org/10.1038/srep41447 |