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Intermolecular oxidative decarbonylative [2 + 2 + 2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary and secondary alkyl aldehydes involving C(sp(3))–H functionalization

A new metal-free oxidative decarbonylative [2 + 2 + 2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary and secondary alkyl aldehydes is described. This reaction enables the formation of three new C–C bonds in a single reaction by a sequence of oxidative decarbonylation, radical additi...

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Detalles Bibliográficos
Autores principales: Li, Yang, Pan, Gao-Hui, Hu, Ming, Liu, Bang, Song, Ren-Jie, Li, Jin-Heng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5282743/
https://www.ncbi.nlm.nih.gov/pubmed/28337339
http://dx.doi.org/10.1039/c6sc02451c

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