Ideal Gas Thermodynamic Functions For Water

The calculation of ideal gas thermodynamic properties for steam to 10,000 K is examined. Centrifugal effects are included using spectroscopic data for the lowest vibrational levels, with extension to higher bending levels based on estimates from a bending model. Modifications are examined for rotati...

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Detalles Bibliográficos
Autor principal: Woolley, Harold W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1987
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5286976/
http://dx.doi.org/10.6028/jres.092.004
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author Woolley, Harold W.
author_facet Woolley, Harold W.
author_sort Woolley, Harold W.
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description The calculation of ideal gas thermodynamic properties for steam to 10,000 K is examined. Centrifugal effects are included using spectroscopic data for the lowest vibrational levels, with extension to higher bending levels based on estimates from a bending model. Modifications are examined for rotational and vibrational cut-off effects. Uncertainties in obtaining a suitably regularized representation of energy versus bond stretching vibration in approaching the dissociation energy region appear relevant to the reliability of the extrapolation.
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spelling pubmed-52869762021-08-02 Ideal Gas Thermodynamic Functions For Water Woolley, Harold W. J Res Natl Bur Stand (1977) Article The calculation of ideal gas thermodynamic properties for steam to 10,000 K is examined. Centrifugal effects are included using spectroscopic data for the lowest vibrational levels, with extension to higher bending levels based on estimates from a bending model. Modifications are examined for rotational and vibrational cut-off effects. Uncertainties in obtaining a suitably regularized representation of energy versus bond stretching vibration in approaching the dissociation energy region appear relevant to the reliability of the extrapolation. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1987 1987-02-01 /pmc/articles/PMC5286976/ http://dx.doi.org/10.6028/jres.092.004 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Woolley, Harold W.
Ideal Gas Thermodynamic Functions For Water
title Ideal Gas Thermodynamic Functions For Water
title_full Ideal Gas Thermodynamic Functions For Water
title_fullStr Ideal Gas Thermodynamic Functions For Water
title_full_unstemmed Ideal Gas Thermodynamic Functions For Water
title_short Ideal Gas Thermodynamic Functions For Water
title_sort ideal gas thermodynamic functions for water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5286976/
http://dx.doi.org/10.6028/jres.092.004
work_keys_str_mv AT woolleyharoldw idealgasthermodynamicfunctionsforwater

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