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Dissociation Constant of Anisic (p-Methoxybenzoic) Acid in the System Ethanol-Water at 25 °C

The dissociation constant of anisic (p-methoxybenzoic) acid in the system ethanol-water was measured at 25° C by a combination of spectrophotometric and electrometric methods. Percentage by weight of ethanol in the solvent system varied from zero to 83.43. The value of K varied correspondingly from...

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Detalles Bibliográficos
Autores principales: Sager, Elizabeth E., Bower, Vincent E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1960
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287090/
https://www.ncbi.nlm.nih.gov/pubmed/32196174
http://dx.doi.org/10.6028/jres.064A.035
Descripción
Sumario:The dissociation constant of anisic (p-methoxybenzoic) acid in the system ethanol-water was measured at 25° C by a combination of spectrophotometric and electrometric methods. Percentage by weight of ethanol in the solvent system varied from zero to 83.43. The value of K varied correspondingly from 3.22×10(−5) (pK=4.492) to 3.34×10(−8) (pK = 7.476).