Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t

Methods are presented for the preparation of d-glucose-6-t, d-xylose-5-t, and d-mannitol-1-t by the reduction of suitable compounds with lithium borohydride-t in anhydrous tetrahydrofuran, followed by hydrolysis of the products. The starting materials for the reductions are, respectively, 1,2-O-isop...

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Detalles Bibliográficos
Autores principales: Isbell, Horace S., Frush, Harriet L., Moyer, Joseph D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1960
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287092/
https://www.ncbi.nlm.nih.gov/pubmed/32196176
http://dx.doi.org/10.6028/jres.064A.037
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author Isbell, Horace S.
Frush, Harriet L.
Moyer, Joseph D.
author_facet Isbell, Horace S.
Frush, Harriet L.
Moyer, Joseph D.
author_sort Isbell, Horace S.
collection PubMed
description Methods are presented for the preparation of d-glucose-6-t, d-xylose-5-t, and d-mannitol-1-t by the reduction of suitable compounds with lithium borohydride-t in anhydrous tetrahydrofuran, followed by hydrolysis of the products. The starting materials for the reductions are, respectively, 1,2-O-isopropylidene-d-glucurono-6,3-lactone, 5-aldo-1,2-O-isopropylidene-d-xylo-pentofuranose, and 2,3:5,6-di-O-isopropylidene-d-mannofuranose. The apparatus and procedure for carrying out the reductions in a closed system are described.
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spelling pubmed-52870922020-03-18 Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t Isbell, Horace S. Frush, Harriet L. Moyer, Joseph D. J Res Natl Bur Stand A Phys Chem Article Methods are presented for the preparation of d-glucose-6-t, d-xylose-5-t, and d-mannitol-1-t by the reduction of suitable compounds with lithium borohydride-t in anhydrous tetrahydrofuran, followed by hydrolysis of the products. The starting materials for the reductions are, respectively, 1,2-O-isopropylidene-d-glucurono-6,3-lactone, 5-aldo-1,2-O-isopropylidene-d-xylo-pentofuranose, and 2,3:5,6-di-O-isopropylidene-d-mannofuranose. The apparatus and procedure for carrying out the reductions in a closed system are described. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1960 1960-08-01 /pmc/articles/PMC5287092/ /pubmed/32196176 http://dx.doi.org/10.6028/jres.064A.037 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Isbell, Horace S.
Frush, Harriet L.
Moyer, Joseph D.
Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t
title Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t
title_full Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t
title_fullStr Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t
title_full_unstemmed Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t
title_short Tritium-Labeled Compounds IV. d-Glucose-6-t, d-Xylose-5-t, and d-Mannitol-1-t
title_sort tritium-labeled compounds iv. d-glucose-6-t, d-xylose-5-t, and d-mannitol-1-t
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287092/
https://www.ncbi.nlm.nih.gov/pubmed/32196176
http://dx.doi.org/10.6028/jres.064A.037
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