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Some Vibrational-Rotational Bands of Deuterated Methanes
A parallel band at 2,200 cm(−1) and a perpendicular band at 2,780 cm(−1) of CH(3)D have been observed under high resolution and analysed. The analysis of the perpendicular band revealed the presence of l-type doubling in the doubly degenerate excited state. From the analysis of the parallel band it...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
[Gaithersburg, MD] : U.S. Dept. of Commerce, National
Institute of Standards and Technology
1959
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287196/ https://www.ncbi.nlm.nih.gov/pubmed/31216145 http://dx.doi.org/10.6028/jres.063A.007 |
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author | Allen, Harry C. Plyler, Earle K. |
author_facet | Allen, Harry C. Plyler, Earle K. |
author_sort | Allen, Harry C. |
collection | PubMed |
description | A parallel band at 2,200 cm(−1) and a perpendicular band at 2,780 cm(−1) of CH(3)D have been observed under high resolution and analysed. The analysis of the perpendicular band revealed the presence of l-type doubling in the doubly degenerate excited state. From the analysis of the parallel band it is found that B(0)= 3.880 cm(−1). A hybrid band of CD(3)H has been observed near 2,600 cm(−1). Both active components, A and E are observed and analysed. The ground state B(0) value found from this analysis is in good agreement with previous determinations. |
format | Online Article Text |
id | pubmed-5287196 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 1959 |
publisher | [Gaithersburg, MD] : U.S. Dept. of Commerce, National
Institute of Standards and Technology |
record_format | MEDLINE/PubMed |
spelling | pubmed-52871962019-06-18 Some Vibrational-Rotational Bands of Deuterated Methanes Allen, Harry C. Plyler, Earle K. J Res Natl Bur Stand A Phys Chem Article A parallel band at 2,200 cm(−1) and a perpendicular band at 2,780 cm(−1) of CH(3)D have been observed under high resolution and analysed. The analysis of the perpendicular band revealed the presence of l-type doubling in the doubly degenerate excited state. From the analysis of the parallel band it is found that B(0)= 3.880 cm(−1). A hybrid band of CD(3)H has been observed near 2,600 cm(−1). Both active components, A and E are observed and analysed. The ground state B(0) value found from this analysis is in good agreement with previous determinations. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1959 1959-10-01 /pmc/articles/PMC5287196/ /pubmed/31216145 http://dx.doi.org/10.6028/jres.063A.007 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright. |
spellingShingle | Article Allen, Harry C. Plyler, Earle K. Some Vibrational-Rotational Bands of Deuterated Methanes |
title | Some Vibrational-Rotational Bands of Deuterated Methanes |
title_full | Some Vibrational-Rotational Bands of Deuterated Methanes |
title_fullStr | Some Vibrational-Rotational Bands of Deuterated Methanes |
title_full_unstemmed | Some Vibrational-Rotational Bands of Deuterated Methanes |
title_short | Some Vibrational-Rotational Bands of Deuterated Methanes |
title_sort | some vibrational-rotational bands of deuterated methanes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287196/ https://www.ncbi.nlm.nih.gov/pubmed/31216145 http://dx.doi.org/10.6028/jres.063A.007 |
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