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Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses

The infrared absorption spectra of five N-glycopyranosylacetamides and of six acetate esters thereof are presented, together with the spectra of five related compounds, for the range of 5000 to 250 cm(−1). Analysis of the spectra permitted assignment of characteristic group-frequencies. For comparis...

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Detalles Bibliográficos
Autores principales: Tipson, R. Stuart, Isbell, Horace S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287210/
https://www.ncbi.nlm.nih.gov/pubmed/32196193
http://dx.doi.org/10.6028/jres.065A.002
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author Tipson, R. Stuart
Isbell, Horace S.
author_facet Tipson, R. Stuart
Isbell, Horace S.
author_sort Tipson, R. Stuart
collection PubMed
description The infrared absorption spectra of five N-glycopyranosylacetamides and of six acetate esters thereof are presented, together with the spectra of five related compounds, for the range of 5000 to 250 cm(−1). Analysis of the spectra permitted assignment of characteristic group-frequencies. For comparison, the spectra of eight reducing, pyranose acetates are also given. The general effect (on the spectra) of changing the anomeric group from hydroxyl to (a) acetamido and (b) methoxyl, when all (other) hydroxyl groups are acetylated, is pointed out.
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spelling pubmed-52872102020-03-18 Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses Tipson, R. Stuart Isbell, Horace S. J Res Natl Bur Stand A Phys Chem Article The infrared absorption spectra of five N-glycopyranosylacetamides and of six acetate esters thereof are presented, together with the spectra of five related compounds, for the range of 5000 to 250 cm(−1). Analysis of the spectra permitted assignment of characteristic group-frequencies. For comparison, the spectra of eight reducing, pyranose acetates are also given. The general effect (on the spectra) of changing the anomeric group from hydroxyl to (a) acetamido and (b) methoxyl, when all (other) hydroxyl groups are acetylated, is pointed out. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961 1961-02-01 /pmc/articles/PMC5287210/ /pubmed/32196193 http://dx.doi.org/10.6028/jres.065A.002 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Tipson, R. Stuart
Isbell, Horace S.
Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses
title Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses
title_full Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses
title_fullStr Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses
title_full_unstemmed Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses
title_short Infrared Absorption Spectra of Some 1-Acetamido Pyranoid Derivatives and Reducing, Acetylated Pyranoses
title_sort infrared absorption spectra of some 1-acetamido pyranoid derivatives and reducing, acetylated pyranoses
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287210/
https://www.ncbi.nlm.nih.gov/pubmed/32196193
http://dx.doi.org/10.6028/jres.065A.002
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