Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)

Appearance potentia’s have been measured for selected ions from NF(2), NF(3), N(2)F(2), and N(2)F(4). Ionization-dissociation processes are identified and bond dissociation energies are calculated. In addition, the bond dissociation energy, D(F(2)N–NF(2)), has been directly measured to be 5.14±0.38...

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Detalles Bibliográficos
Autores principales: Herron, John T., Dibeler, Vernon H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287248/
https://www.ncbi.nlm.nih.gov/pubmed/32196210
http://dx.doi.org/10.6028/jres.065A.041
Descripción
Sumario:Appearance potentia’s have been measured for selected ions from NF(2), NF(3), N(2)F(2), and N(2)F(4). Ionization-dissociation processes are identified and bond dissociation energies are calculated. In addition, the bond dissociation energy, D(F(2)N–NF(2)), has been directly measured to be 5.14±0.38 kj/mole (21.5± 1.6 kcal/mole). A summary is made of available thermochemical and mass spectrometric data for N–F compounds and some evidence is presented to support the designation of cis and trans structures for the N(2)F(2) isomers.

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