Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)

Appearance potentia’s have been measured for selected ions from NF(2), NF(3), N(2)F(2), and N(2)F(4). Ionization-dissociation processes are identified and bond dissociation energies are calculated. In addition, the bond dissociation energy, D(F(2)N–NF(2)), has been directly measured to be 5.14±0.38...

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Detalles Bibliográficos
Autores principales: Herron, John T., Dibeler, Vernon H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287248/
https://www.ncbi.nlm.nih.gov/pubmed/32196210
http://dx.doi.org/10.6028/jres.065A.041
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author Herron, John T.
Dibeler, Vernon H.
author_facet Herron, John T.
Dibeler, Vernon H.
author_sort Herron, John T.
collection PubMed
description Appearance potentia’s have been measured for selected ions from NF(2), NF(3), N(2)F(2), and N(2)F(4). Ionization-dissociation processes are identified and bond dissociation energies are calculated. In addition, the bond dissociation energy, D(F(2)N–NF(2)), has been directly measured to be 5.14±0.38 kj/mole (21.5± 1.6 kcal/mole). A summary is made of available thermochemical and mass spectrometric data for N–F compounds and some evidence is presented to support the designation of cis and trans structures for the N(2)F(2) isomers.
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spelling pubmed-52872482020-03-18 Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4) Herron, John T. Dibeler, Vernon H. J Res Natl Bur Stand A Phys Chem Article Appearance potentia’s have been measured for selected ions from NF(2), NF(3), N(2)F(2), and N(2)F(4). Ionization-dissociation processes are identified and bond dissociation energies are calculated. In addition, the bond dissociation energy, D(F(2)N–NF(2)), has been directly measured to be 5.14±0.38 kj/mole (21.5± 1.6 kcal/mole). A summary is made of available thermochemical and mass spectrometric data for N–F compounds and some evidence is presented to support the designation of cis and trans structures for the N(2)F(2) isomers. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961 1961-10-01 /pmc/articles/PMC5287248/ /pubmed/32196210 http://dx.doi.org/10.6028/jres.065A.041 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Herron, John T.
Dibeler, Vernon H.
Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)
title Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)
title_full Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)
title_fullStr Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)
title_full_unstemmed Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)
title_short Mass Spectrometric Study of NF(2), NF(3), N(2)F(2), and N(2)F(4)
title_sort mass spectrometric study of nf(2), nf(3), n(2)f(2), and n(2)f(4)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287248/
https://www.ncbi.nlm.nih.gov/pubmed/32196210
http://dx.doi.org/10.6028/jres.065A.041
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