Heats of Hydrolysis and Formation of Dimethoxychloroborane

The heat of hydrolysis of dimethoxychloroborane has been measured; for the reaction, [Formula: see text] From this, we have calculated the heat of formation of dimethoxychloroborane: for the liquid, ΔHf° (25 °C) = −782.1 ± 1.8 kj/mole (−186.9±0.4 kcal/mole), and for the gas, ΔHf° (25 °C) = −747.9 ±2...

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Detalles Bibliográficos
Autores principales: Kilday, Marthada V., Johnson, Walter H., Prosen, Edward J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287252/
https://www.ncbi.nlm.nih.gov/pubmed/32196214
http://dx.doi.org/10.6028/jres.065A.045
Descripción
Sumario:The heat of hydrolysis of dimethoxychloroborane has been measured; for the reaction, [Formula: see text] From this, we have calculated the heat of formation of dimethoxychloroborane: for the liquid, ΔHf° (25 °C) = −782.1 ± 1.8 kj/mole (−186.9±0.4 kcal/mole), and for the gas, ΔHf° (25 °C) = −747.9 ±2.2 kj/mole (−178.8±0.5 kcal/mole).

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