Heats of Hydrolysis and Formation of Dimethoxychloroborane

The heat of hydrolysis of dimethoxychloroborane has been measured; for the reaction, [Formula: see text] From this, we have calculated the heat of formation of dimethoxychloroborane: for the liquid, ΔHf° (25 °C) = −782.1 ± 1.8 kj/mole (−186.9±0.4 kcal/mole), and for the gas, ΔHf° (25 °C) = −747.9 ±2...

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Detalles Bibliográficos
Autores principales: Kilday, Marthada V., Johnson, Walter H., Prosen, Edward J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287252/
https://www.ncbi.nlm.nih.gov/pubmed/32196214
http://dx.doi.org/10.6028/jres.065A.045
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author Kilday, Marthada V.
Johnson, Walter H.
Prosen, Edward J.
author_facet Kilday, Marthada V.
Johnson, Walter H.
Prosen, Edward J.
author_sort Kilday, Marthada V.
collection PubMed
description The heat of hydrolysis of dimethoxychloroborane has been measured; for the reaction, [Formula: see text] From this, we have calculated the heat of formation of dimethoxychloroborane: for the liquid, ΔHf° (25 °C) = −782.1 ± 1.8 kj/mole (−186.9±0.4 kcal/mole), and for the gas, ΔHf° (25 °C) = −747.9 ±2.2 kj/mole (−178.8±0.5 kcal/mole).
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spelling pubmed-52872522020-03-18 Heats of Hydrolysis and Formation of Dimethoxychloroborane Kilday, Marthada V. Johnson, Walter H. Prosen, Edward J. J Res Natl Bur Stand A Phys Chem Article The heat of hydrolysis of dimethoxychloroborane has been measured; for the reaction, [Formula: see text] From this, we have calculated the heat of formation of dimethoxychloroborane: for the liquid, ΔHf° (25 °C) = −782.1 ± 1.8 kj/mole (−186.9±0.4 kcal/mole), and for the gas, ΔHf° (25 °C) = −747.9 ±2.2 kj/mole (−178.8±0.5 kcal/mole). [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961 1961-10-01 /pmc/articles/PMC5287252/ /pubmed/32196214 http://dx.doi.org/10.6028/jres.065A.045 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Kilday, Marthada V.
Johnson, Walter H.
Prosen, Edward J.
Heats of Hydrolysis and Formation of Dimethoxychloroborane
title Heats of Hydrolysis and Formation of Dimethoxychloroborane
title_full Heats of Hydrolysis and Formation of Dimethoxychloroborane
title_fullStr Heats of Hydrolysis and Formation of Dimethoxychloroborane
title_full_unstemmed Heats of Hydrolysis and Formation of Dimethoxychloroborane
title_short Heats of Hydrolysis and Formation of Dimethoxychloroborane
title_sort heats of hydrolysis and formation of dimethoxychloroborane
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287252/
https://www.ncbi.nlm.nih.gov/pubmed/32196214
http://dx.doi.org/10.6028/jres.065A.045
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