Heats of Hydrolysis and Formation of Potassium Borohydride

The heat of reaction of potassium borohydride with 0.060 molal HCl has been measured by solution calorimetry. The heat of solution of the hydrolysis products has also been measured and combined with certain literature values to calculate the process: [Formula: see text] A combination of this value w...

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Detalles Bibliográficos
Autores principales: Johnson, Walter H., Schumm, Richard H., Wilson, Isa H., Prosen, Edward J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287272/
https://www.ncbi.nlm.nih.gov/pubmed/32196230
http://dx.doi.org/10.6028/jres.065A.011
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author Johnson, Walter H.
Schumm, Richard H.
Wilson, Isa H.
Prosen, Edward J.
author_facet Johnson, Walter H.
Schumm, Richard H.
Wilson, Isa H.
Prosen, Edward J.
author_sort Johnson, Walter H.
collection PubMed
description The heat of reaction of potassium borohydride with 0.060 molal HCl has been measured by solution calorimetry. The heat of solution of the hydrolysis products has also been measured and combined with certain literature values to calculate the process: [Formula: see text] A combination of this value with literature values for the heats of formation of HCl(g), H(2)O(liq), KCl(c), and H(3)BO(3)(c) gives for KBH(4)(c): [Formula: see text] Other data on the heats of formation of the alkali-metal borohydrides are discussed briefly.
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spelling pubmed-52872722020-03-18 Heats of Hydrolysis and Formation of Potassium Borohydride Johnson, Walter H. Schumm, Richard H. Wilson, Isa H. Prosen, Edward J. J Res Natl Bur Stand A Phys Chem Article The heat of reaction of potassium borohydride with 0.060 molal HCl has been measured by solution calorimetry. The heat of solution of the hydrolysis products has also been measured and combined with certain literature values to calculate the process: [Formula: see text] A combination of this value with literature values for the heats of formation of HCl(g), H(2)O(liq), KCl(c), and H(3)BO(3)(c) gives for KBH(4)(c): [Formula: see text] Other data on the heats of formation of the alkali-metal borohydrides are discussed briefly. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1961 1961-04-01 /pmc/articles/PMC5287272/ /pubmed/32196230 http://dx.doi.org/10.6028/jres.065A.011 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Johnson, Walter H.
Schumm, Richard H.
Wilson, Isa H.
Prosen, Edward J.
Heats of Hydrolysis and Formation of Potassium Borohydride
title Heats of Hydrolysis and Formation of Potassium Borohydride
title_full Heats of Hydrolysis and Formation of Potassium Borohydride
title_fullStr Heats of Hydrolysis and Formation of Potassium Borohydride
title_full_unstemmed Heats of Hydrolysis and Formation of Potassium Borohydride
title_short Heats of Hydrolysis and Formation of Potassium Borohydride
title_sort heats of hydrolysis and formation of potassium borohydride
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287272/
https://www.ncbi.nlm.nih.gov/pubmed/32196230
http://dx.doi.org/10.6028/jres.065A.011
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AT prosenedwardj heatsofhydrolysisandformationofpotassiumborohydride

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