Heat of Formation of Titanium Trichloride

A calorimetric comparison of the heat of hydrolysis of TiCl(4)(liq) with the heat of oxidation and hydrolysis of TiCl(3)(c) has been made. The following value is reported for the combination of these data according to the process: [Formula: see text] A combination of this value with −192.3 ±0.7 kcal...

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Detalles Bibliográficos
Autores principales: Johnson, Walter H., Gilliland, Alexis A., Prosen, Edward J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1960
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287342/
https://www.ncbi.nlm.nih.gov/pubmed/32196252
http://dx.doi.org/10.6028/jres.064A.051
Descripción
Sumario:A calorimetric comparison of the heat of hydrolysis of TiCl(4)(liq) with the heat of oxidation and hydrolysis of TiCl(3)(c) has been made. The following value is reported for the combination of these data according to the process: [Formula: see text] A combination of this value with −192.3 ±0.7 kcal/mole for the heat of formation of TiCl(4)(liq) and with the standard heats of formation of HCl(g) and HI(g) gives for TiCl(3)(c), ΔHf°(25 °C) = −172.4±0.8 kcal/mole.

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