Heat of Formation of Titanium Trichloride

A calorimetric comparison of the heat of hydrolysis of TiCl(4)(liq) with the heat of oxidation and hydrolysis of TiCl(3)(c) has been made. The following value is reported for the combination of these data according to the process: [Formula: see text] A combination of this value with −192.3 ±0.7 kcal...

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Detalles Bibliográficos
Autores principales: Johnson, Walter H., Gilliland, Alexis A., Prosen, Edward J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1960
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287342/
https://www.ncbi.nlm.nih.gov/pubmed/32196252
http://dx.doi.org/10.6028/jres.064A.051
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author Johnson, Walter H.
Gilliland, Alexis A.
Prosen, Edward J.
author_facet Johnson, Walter H.
Gilliland, Alexis A.
Prosen, Edward J.
author_sort Johnson, Walter H.
collection PubMed
description A calorimetric comparison of the heat of hydrolysis of TiCl(4)(liq) with the heat of oxidation and hydrolysis of TiCl(3)(c) has been made. The following value is reported for the combination of these data according to the process: [Formula: see text] A combination of this value with −192.3 ±0.7 kcal/mole for the heat of formation of TiCl(4)(liq) and with the standard heats of formation of HCl(g) and HI(g) gives for TiCl(3)(c), ΔHf°(25 °C) = −172.4±0.8 kcal/mole.
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spelling pubmed-52873422020-03-18 Heat of Formation of Titanium Trichloride Johnson, Walter H. Gilliland, Alexis A. Prosen, Edward J. J Res Natl Bur Stand A Phys Chem Article A calorimetric comparison of the heat of hydrolysis of TiCl(4)(liq) with the heat of oxidation and hydrolysis of TiCl(3)(c) has been made. The following value is reported for the combination of these data according to the process: [Formula: see text] A combination of this value with −192.3 ±0.7 kcal/mole for the heat of formation of TiCl(4)(liq) and with the standard heats of formation of HCl(g) and HI(g) gives for TiCl(3)(c), ΔHf°(25 °C) = −172.4±0.8 kcal/mole. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1960 1960-12-01 /pmc/articles/PMC5287342/ /pubmed/32196252 http://dx.doi.org/10.6028/jres.064A.051 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Johnson, Walter H.
Gilliland, Alexis A.
Prosen, Edward J.
Heat of Formation of Titanium Trichloride
title Heat of Formation of Titanium Trichloride
title_full Heat of Formation of Titanium Trichloride
title_fullStr Heat of Formation of Titanium Trichloride
title_full_unstemmed Heat of Formation of Titanium Trichloride
title_short Heat of Formation of Titanium Trichloride
title_sort heat of formation of titanium trichloride
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287342/
https://www.ncbi.nlm.nih.gov/pubmed/32196252
http://dx.doi.org/10.6028/jres.064A.051
work_keys_str_mv AT johnsonwalterh heatofformationoftitaniumtrichloride
AT gillilandalexisa heatofformationoftitaniumtrichloride
AT prosenedwardj heatofformationoftitaniumtrichloride

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