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Spectrophotometric Determination of the Ionization Constant of Dimethylpicric Acid (2,4,6-Trinitro-3,5-xylenol) in Water at 25 °C
The ionization constant of dimethylpicric acid (2,4,6-trinitro-3,5-xylenol) in water at 25 °C has been determined by a spectrophotometric method. The pK value 1.38 (K ≈0.042) was obtained. Potentiometric titrations, although less precise, yielded a pK value of the same magnitude.
Autores principales: | Davis, Marion Maclean, Paabo, Maya, Robinson, Robert A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1960
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5287345/ https://www.ncbi.nlm.nih.gov/pubmed/32196255 http://dx.doi.org/10.6028/jres.064A.054 |
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