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ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores

Unique donor–π–acceptor phthalocyanines have been synthesized through the asymmetric functionalization of an ABAB phthalocyanine, crosswise functionalized with two iodine atoms through Pd‐catalyzed cross‐coupling reactions with adequate electron‐donor and electron‐acceptor moieties. These push–pull...

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Autores principales: Fazio, Ettore, Jaramillo‐García, Javier, Medel, María, Urbani, Maxence, Grätzel, Michael, Nazeerudin, Mohammad K., de la Torre, Gema, Torres, Tomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5288760/
https://www.ncbi.nlm.nih.gov/pubmed/28168157
http://dx.doi.org/10.1002/open.201600113
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author Fazio, Ettore
Jaramillo‐García, Javier
Medel, María
Urbani, Maxence
Grätzel, Michael
Nazeerudin, Mohammad K.
de la Torre, Gema
Torres, Tomas
author_facet Fazio, Ettore
Jaramillo‐García, Javier
Medel, María
Urbani, Maxence
Grätzel, Michael
Nazeerudin, Mohammad K.
de la Torre, Gema
Torres, Tomas
author_sort Fazio, Ettore
collection PubMed
description Unique donor–π–acceptor phthalocyanines have been synthesized through the asymmetric functionalization of an ABAB phthalocyanine, crosswise functionalized with two iodine atoms through Pd‐catalyzed cross‐coupling reactions with adequate electron‐donor and electron‐acceptor moieties. These push–pull molecules have been optically and electrochemically characterized, and their ability to perform as chromophores for dye‐sensitized solar cells has been tested.
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spelling pubmed-52887602017-02-06 ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores Fazio, Ettore Jaramillo‐García, Javier Medel, María Urbani, Maxence Grätzel, Michael Nazeerudin, Mohammad K. de la Torre, Gema Torres, Tomas ChemistryOpen Full Papers Unique donor–π–acceptor phthalocyanines have been synthesized through the asymmetric functionalization of an ABAB phthalocyanine, crosswise functionalized with two iodine atoms through Pd‐catalyzed cross‐coupling reactions with adequate electron‐donor and electron‐acceptor moieties. These push–pull molecules have been optically and electrochemically characterized, and their ability to perform as chromophores for dye‐sensitized solar cells has been tested. John Wiley and Sons Inc. 2016-12-27 /pmc/articles/PMC5288760/ /pubmed/28168157 http://dx.doi.org/10.1002/open.201600113 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Fazio, Ettore
Jaramillo‐García, Javier
Medel, María
Urbani, Maxence
Grätzel, Michael
Nazeerudin, Mohammad K.
de la Torre, Gema
Torres, Tomas
ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores
title ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores
title_full ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores
title_fullStr ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores
title_full_unstemmed ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores
title_short ABAB Phthalocyanines: Scaffolds for Building Unprecedented Donor–π–Acceptor Chromophores
title_sort abab phthalocyanines: scaffolds for building unprecedented donor–π–acceptor chromophores
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5288760/
https://www.ncbi.nlm.nih.gov/pubmed/28168157
http://dx.doi.org/10.1002/open.201600113
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