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Roaming‐Mediated CH(2)NH Elimination from the Ionization of Aromatic Ethylamines

The ionization of aromatic ethylamines by photons or electrons leads to elimination of CH(2)NH fragments, supposedly deriving from the McLafferty rearrangement involving intramolecular γ‐hydrogen transfer. Using tryptamine and phenethylamine as examples, the results reported here suggest that the Mc...

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Detalles Bibliográficos
Autores principales: Zhang, Mengxing, Guo, Huijun, Zhang, Lidong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5288767/
https://www.ncbi.nlm.nih.gov/pubmed/28168149
http://dx.doi.org/10.1002/open.201600144