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Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-dinitrophenyl)hydrazinylidene]methyl}phenol
The essential part (including all the non-hydrogen atoms except two methyl carbons) of the molecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bisects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intramolecul...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290541/ https://www.ncbi.nlm.nih.gov/pubmed/28217318 http://dx.doi.org/10.1107/S2056989016020107 |
Sumario: | The essential part (including all the non-hydrogen atoms except two methyl carbons) of the molecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bisects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intramolecular N—H⋯O hydrogen bond present, forming an S(6) ring motif. In the crystal, molecules are linked via O—H⋯O hydrogen bonds, forming zigzag chains propagating along the a-axis direction. There are no other significant intermolecular contacts present. |
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