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Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol

The essential part (including all the non-hydrogen atoms except two methyl carbons) of the mol­ecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bis­ects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intra­molecul...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Dege, Necmi, Haque, Ashanul, Kalibabchuk, Valentina A., Cemberci, Mustafa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290541/
https://www.ncbi.nlm.nih.gov/pubmed/28217318
http://dx.doi.org/10.1107/S2056989016020107
Descripción
Sumario:The essential part (including all the non-hydrogen atoms except two methyl carbons) of the mol­ecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bis­ects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intra­molecular N—H⋯O hydrogen bond present, forming an S(6) ring motif. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, forming zigzag chains propagating along the a-axis direction. There are no other significant inter­molecular contacts present.