Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol

The essential part (including all the non-hydrogen atoms except two methyl carbons) of the mol­ecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bis­ects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intra­molecul...

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Autores principales: Faizi, Md. Serajul Haque, Dege, Necmi, Haque, Ashanul, Kalibabchuk, Valentina A., Cemberci, Mustafa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290541/
https://www.ncbi.nlm.nih.gov/pubmed/28217318
http://dx.doi.org/10.1107/S2056989016020107
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author Faizi, Md. Serajul Haque
Dege, Necmi
Haque, Ashanul
Kalibabchuk, Valentina A.
Cemberci, Mustafa
author_facet Faizi, Md. Serajul Haque
Dege, Necmi
Haque, Ashanul
Kalibabchuk, Valentina A.
Cemberci, Mustafa
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The essential part (including all the non-hydrogen atoms except two methyl carbons) of the mol­ecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bis­ects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intra­molecular N—H⋯O hydrogen bond present, forming an S(6) ring motif. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, forming zigzag chains propagating along the a-axis direction. There are no other significant inter­molecular contacts present.
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spelling pubmed-52905412017-02-17 Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol Faizi, Md. Serajul Haque Dege, Necmi Haque, Ashanul Kalibabchuk, Valentina A. Cemberci, Mustafa Acta Crystallogr E Crystallogr Commun Research Communications The essential part (including all the non-hydrogen atoms except two methyl carbons) of the mol­ecule of the title compound, C(21)H(26)N(4)O(5), lies on a mirror plane, which bis­ects the t-butyl groups. The conformation of the C=N bond of this Schiff base compound is E, and there is an intra­molecular N—H⋯O hydrogen bond present, forming an S(6) ring motif. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, forming zigzag chains propagating along the a-axis direction. There are no other significant inter­molecular contacts present. International Union of Crystallography 2017-01-06 /pmc/articles/PMC5290541/ /pubmed/28217318 http://dx.doi.org/10.1107/S2056989016020107 Text en © Faizi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Dege, Necmi
Haque, Ashanul
Kalibabchuk, Valentina A.
Cemberci, Mustafa
Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
title Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
title_full Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
title_fullStr Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
title_full_unstemmed Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
title_short Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
title_sort crystal structure of (e)-2,6-di-tert-butyl-4-{[2-(2,4-di­nitro­phen­yl)hydrazinylidene]meth­yl}phenol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290541/
https://www.ncbi.nlm.nih.gov/pubmed/28217318
http://dx.doi.org/10.1107/S2056989016020107
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