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Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene
The title compound, C(50)H(44), 1, was synthesized as a derivative of heptazethrene bearing two methyl and two tert-butylphenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. Albeit remote...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290542/ https://www.ncbi.nlm.nih.gov/pubmed/28217319 http://dx.doi.org/10.1107/S2056989016020247 |
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author | Kamata, Sho Sato, Sota Wu, Jishan Isobe, Hiroyuki |
author_facet | Kamata, Sho Sato, Sota Wu, Jishan Isobe, Hiroyuki |
author_sort | Kamata, Sho |
collection | PubMed |
description | The title compound, C(50)H(44), 1, was synthesized as a derivative of heptazethrene bearing two methyl and two tert-butylphenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the heptazethrene plane. The tert-butylphenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09 (5)° between the phenalene ring system and the substituted benzene ring, and prevent direct intermolecular contacts of the heptazethrene cores. |
format | Online Article Text |
id | pubmed-5290542 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-52905422017-02-17 Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene Kamata, Sho Sato, Sota Wu, Jishan Isobe, Hiroyuki Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(50)H(44), 1, was synthesized as a derivative of heptazethrene bearing two methyl and two tert-butylphenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the heptazethrene plane. The tert-butylphenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09 (5)° between the phenalene ring system and the substituted benzene ring, and prevent direct intermolecular contacts of the heptazethrene cores. International Union of Crystallography 2017-01-06 /pmc/articles/PMC5290542/ /pubmed/28217319 http://dx.doi.org/10.1107/S2056989016020247 Text en © Kamata et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Kamata, Sho Sato, Sota Wu, Jishan Isobe, Hiroyuki Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
title | Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
title_full | Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
title_fullStr | Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
title_full_unstemmed | Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
title_short | Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
title_sort | crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290542/ https://www.ncbi.nlm.nih.gov/pubmed/28217319 http://dx.doi.org/10.1107/S2056989016020247 |
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