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Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene

The title compound, C(50)H(44), 1, was synthesized as a derivative of hepta­zethrene bearing two methyl and two tert-butyl­phenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. Albeit remote...

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Detalles Bibliográficos
Autores principales: Kamata, Sho, Sato, Sota, Wu, Jishan, Isobe, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290542/
https://www.ncbi.nlm.nih.gov/pubmed/28217319
http://dx.doi.org/10.1107/S2056989016020247
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author Kamata, Sho
Sato, Sota
Wu, Jishan
Isobe, Hiroyuki
author_facet Kamata, Sho
Sato, Sota
Wu, Jishan
Isobe, Hiroyuki
author_sort Kamata, Sho
collection PubMed
description The title compound, C(50)H(44), 1, was synthesized as a derivative of hepta­zethrene bearing two methyl and two tert-butyl­phenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the hepta­zethrene plane. The tert-butyl­phenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09 (5)° between the phenalene ring system and the substituted benzene ring, and prevent direct inter­molecular contacts of the hepta­zethrene cores.
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spelling pubmed-52905422017-02-17 Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene Kamata, Sho Sato, Sota Wu, Jishan Isobe, Hiroyuki Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(50)H(44), 1, was synthesized as a derivative of hepta­zethrene bearing two methyl and two tert-butyl­phenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the hepta­zethrene plane. The tert-butyl­phenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09 (5)° between the phenalene ring system and the substituted benzene ring, and prevent direct inter­molecular contacts of the hepta­zethrene cores. International Union of Crystallography 2017-01-06 /pmc/articles/PMC5290542/ /pubmed/28217319 http://dx.doi.org/10.1107/S2056989016020247 Text en © Kamata et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Kamata, Sho
Sato, Sota
Wu, Jishan
Isobe, Hiroyuki
Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
title Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
title_full Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
title_fullStr Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
title_full_unstemmed Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
title_short Crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
title_sort crystal structure of 7,15-bis­(4-tert-butyl­phen­yl)-1,9-di­methyl­hepta­zethrene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290542/
https://www.ncbi.nlm.nih.gov/pubmed/28217319
http://dx.doi.org/10.1107/S2056989016020247
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