Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol

In the title compound, C(19)H(15)N(3)O(3), which crystallizes as the phenol–imine tautomer, the dihedral angle between the aromatic rings bridged by the NH unit is 47.16 (16)°. The dihedral angle between the rings bridged by the imine unit is 6.24 (15)°; this near coplanarity is reinforced by an int...

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Autores principales: Faizi, Md. Serajul Haque, Haque, Ashanul, Kalibabchuk, Valentina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290545/
https://www.ncbi.nlm.nih.gov/pubmed/28217322
http://dx.doi.org/10.1107/S2056989016020673
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author Faizi, Md. Serajul Haque
Haque, Ashanul
Kalibabchuk, Valentina A.
author_facet Faizi, Md. Serajul Haque
Haque, Ashanul
Kalibabchuk, Valentina A.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the title compound, C(19)H(15)N(3)O(3), which crystallizes as the phenol–imine tautomer, the dihedral angle between the aromatic rings bridged by the NH unit is 47.16 (16)°. The dihedral angle between the rings bridged by the imine unit is 6.24 (15)°; this near coplanarity is reinforced by an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring. In the crystal, N—H⋯O hydrogen bonds generate [201] C(13) chains. The chains are reinforced and cross-linked by C—H⋯O inter­actions to generate (001) sheets.
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spelling pubmed-52905452017-02-17 Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol Faizi, Md. Serajul Haque Haque, Ashanul Kalibabchuk, Valentina A. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(19)H(15)N(3)O(3), which crystallizes as the phenol–imine tautomer, the dihedral angle between the aromatic rings bridged by the NH unit is 47.16 (16)°. The dihedral angle between the rings bridged by the imine unit is 6.24 (15)°; this near coplanarity is reinforced by an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring. In the crystal, N—H⋯O hydrogen bonds generate [201] C(13) chains. The chains are reinforced and cross-linked by C—H⋯O inter­actions to generate (001) sheets. International Union of Crystallography 2017-01-06 /pmc/articles/PMC5290545/ /pubmed/28217322 http://dx.doi.org/10.1107/S2056989016020673 Text en © Faizi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Haque, Ashanul
Kalibabchuk, Valentina A.
Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
title Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
title_full Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
title_fullStr Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
title_full_unstemmed Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
title_short Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
title_sort crystal structure of (e)-2-{[(4-anilinophen­yl)imino]meth­yl}-4-nitro­phenol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290545/
https://www.ncbi.nlm.nih.gov/pubmed/28217322
http://dx.doi.org/10.1107/S2056989016020673
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