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Crystal structure of (E)-N (1)-[(anthracen-9-yl)methylidene]-N (4)-phenylbenzene-1,4-diamine
The title compound, C(27)H(20)N(2), a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenylenediamine, crystallizes with three independent molecules in the asymmetric unit. The three molecules have slightly varying overall conformations, all...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290551/ https://www.ncbi.nlm.nih.gov/pubmed/28217328 http://dx.doi.org/10.1107/S2056989016020612 |
Sumario: | The title compound, C(27)H(20)N(2), a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenylenediamine, crystallizes with three independent molecules in the asymmetric unit. The three molecules have slightly varying overall conformations, all having trans conformations with respect to the C=N bond. In the crystal, the packing features N—H⋯N hydrogen bonds, which connect molecules into chains extending along the c-axis direction, interlinked by C—H⋯π interactions (minimum H⋯Cg = 2.65 Å) into sheets lying parallel to (001). |
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