Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine

The title compound, C(27)H(20)N(2), a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenyl­enedi­amine, crystallizes with three independent mol­ecules in the asymmetric unit. The three mol­ecules have slightly varying overall conformations, all...

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Autores principales: Faizi, Md. Serajul Haque, Haque, Ashanul, Ahmad, Musheer, Golenya, Irina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290551/
https://www.ncbi.nlm.nih.gov/pubmed/28217328
http://dx.doi.org/10.1107/S2056989016020612
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author Faizi, Md. Serajul Haque
Haque, Ashanul
Ahmad, Musheer
Golenya, Irina A.
author_facet Faizi, Md. Serajul Haque
Haque, Ashanul
Ahmad, Musheer
Golenya, Irina A.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The title compound, C(27)H(20)N(2), a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenyl­enedi­amine, crystallizes with three independent mol­ecules in the asymmetric unit. The three mol­ecules have slightly varying overall conformations, all having trans conformations with respect to the C=N bond. In the crystal, the packing features N—H⋯N hydrogen bonds, which connect mol­ecules into chains extending along the c-axis direction, inter­linked by C—H⋯π inter­actions (minimum H⋯Cg = 2.65 Å) into sheets lying parallel to (001).
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spelling pubmed-52905512017-02-17 Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine Faizi, Md. Serajul Haque Haque, Ashanul Ahmad, Musheer Golenya, Irina A. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(27)H(20)N(2), a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenyl­enedi­amine, crystallizes with three independent mol­ecules in the asymmetric unit. The three mol­ecules have slightly varying overall conformations, all having trans conformations with respect to the C=N bond. In the crystal, the packing features N—H⋯N hydrogen bonds, which connect mol­ecules into chains extending along the c-axis direction, inter­linked by C—H⋯π inter­actions (minimum H⋯Cg = 2.65 Å) into sheets lying parallel to (001). International Union of Crystallography 2017-01-10 /pmc/articles/PMC5290551/ /pubmed/28217328 http://dx.doi.org/10.1107/S2056989016020612 Text en © Faizi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Haque, Ashanul
Ahmad, Musheer
Golenya, Irina A.
Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_full Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_fullStr Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_full_unstemmed Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_short Crystal structure of (E)-N (1)-[(anthracen-9-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_sort crystal structure of (e)-n (1)-[(anthracen-9-yl)methyl­idene]-n (4)-phenyl­benzene-1,4-di­amine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290551/
https://www.ncbi.nlm.nih.gov/pubmed/28217328
http://dx.doi.org/10.1107/S2056989016020612
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