Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide

The crystal structure of the title compound, [Rb(C(18)H(36)N(2)O(6))](3)RbSn(9), consists of deltahedral [Sn(9)](4–) cluster anions, Rb(+) cations and cryptand mol­ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol­ecules, are neighboured directly...

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Detalles Bibliográficos
Autores principales: Klein, Wilhelm, He, Haiyan, Fässler, Thomas F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290553/
https://www.ncbi.nlm.nih.gov/pubmed/28217330
http://dx.doi.org/10.1107/S2056989017000172
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author Klein, Wilhelm
He, Haiyan
Fässler, Thomas F.
author_facet Klein, Wilhelm
He, Haiyan
Fässler, Thomas F.
author_sort Klein, Wilhelm
collection PubMed
description The crystal structure of the title compound, [Rb(C(18)H(36)N(2)O(6))](3)RbSn(9), consists of deltahedral [Sn(9)](4–) cluster anions, Rb(+) cations and cryptand mol­ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol­ecules, are neighboured directly to the [Sn(9)](4–) clusters and inter­connect them to form (∞) (1)[RbSn(9)](3–) chains. These chains extend parallel to [001] and are arranged in a pseudo-hexa­gonal rod packing, separated by the Rb-cryptand complex cations.
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spelling pubmed-52905532017-02-17 Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide Klein, Wilhelm He, Haiyan Fässler, Thomas F. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title compound, [Rb(C(18)H(36)N(2)O(6))](3)RbSn(9), consists of deltahedral [Sn(9)](4–) cluster anions, Rb(+) cations and cryptand mol­ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol­ecules, are neighboured directly to the [Sn(9)](4–) clusters and inter­connect them to form (∞) (1)[RbSn(9)](3–) chains. These chains extend parallel to [001] and are arranged in a pseudo-hexa­gonal rod packing, separated by the Rb-cryptand complex cations. International Union of Crystallography 2017-01-13 /pmc/articles/PMC5290553/ /pubmed/28217330 http://dx.doi.org/10.1107/S2056989017000172 Text en © Klein et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Klein, Wilhelm
He, Haiyan
Fässler, Thomas F.
Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide
title Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide
title_full Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide
title_fullStr Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide
title_full_unstemmed Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide
title_short Crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) N (2),O (6))rubidium] rubidium nona­stannide
title_sort crystal structure of tris[(4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosane-κ(8) n (2),o (6))rubidium] rubidium nona­stannide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290553/
https://www.ncbi.nlm.nih.gov/pubmed/28217330
http://dx.doi.org/10.1107/S2056989017000172
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