Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]

The title compound, {[Cu(2)(C(7)H(4)O(3))(2)(H(2)O)(2)]·2H(2)O}(n), contains two copper(II) cations in special positions (one on a twofold rotation axis and one on an inversion centre) and the the salicylate ligand in its dianionic form. By four- and six-coordinate metal coordination, chains are for...

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Detalles Bibliográficos
Autores principales: van der Horn, Jitschaq A., Lutz, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290573/
https://www.ncbi.nlm.nih.gov/pubmed/28217350
http://dx.doi.org/10.1107/S2056989017000883
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author van der Horn, Jitschaq A.
Lutz, Martin
author_facet van der Horn, Jitschaq A.
Lutz, Martin
author_sort van der Horn, Jitschaq A.
collection PubMed
description The title compound, {[Cu(2)(C(7)H(4)O(3))(2)(H(2)O)(2)]·2H(2)O}(n), contains two copper(II) cations in special positions (one on a twofold rotation axis and one on an inversion centre) and the the salicylate ligand in its dianionic form. By four- and six-coordinate metal coordination, chains are formed parallel to [001], which are extended by O—H⋯O hydrogen bonding into sheets extending parallel to (100). These sheets are weakly connected by O—H⋯O hydrogen bonding via the non-coordinating lattice water mol­ecules into a three-dimensional network.
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spelling pubmed-52905732017-02-17 Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate] van der Horn, Jitschaq A. Lutz, Martin Acta Crystallogr E Crystallogr Commun Research Communications The title compound, {[Cu(2)(C(7)H(4)O(3))(2)(H(2)O)(2)]·2H(2)O}(n), contains two copper(II) cations in special positions (one on a twofold rotation axis and one on an inversion centre) and the the salicylate ligand in its dianionic form. By four- and six-coordinate metal coordination, chains are formed parallel to [001], which are extended by O—H⋯O hydrogen bonding into sheets extending parallel to (100). These sheets are weakly connected by O—H⋯O hydrogen bonding via the non-coordinating lattice water mol­ecules into a three-dimensional network. International Union of Crystallography 2017-01-20 /pmc/articles/PMC5290573/ /pubmed/28217350 http://dx.doi.org/10.1107/S2056989017000883 Text en © Horn and Lutz 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
van der Horn, Jitschaq A.
Lutz, Martin
Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]
title Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]
title_full Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]
title_fullStr Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]
title_full_unstemmed Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]
title_short Crystal structure of catena-poly[[copper(II)-μ(2)-salicylato-[diaqua­copper(II)]-μ(2)-salicylato] dihydrate]
title_sort crystal structure of catena-poly[[copper(ii)-μ(2)-salicylato-[diaqua­copper(ii)]-μ(2)-salicylato] dihydrate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290573/
https://www.ncbi.nlm.nih.gov/pubmed/28217350
http://dx.doi.org/10.1107/S2056989017000883
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