Cargando…

Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis

The complete mol­ecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methyl­ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl grou...

Descripción completa

Detalles Bibliográficos
Autores principales: Mohamad, Rapidah, Awang, Normah, Kamaludin, Nurul F., Jotani, Mukesh M., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290578/
https://www.ncbi.nlm.nih.gov/pubmed/28217355
http://dx.doi.org/10.1107/S2056989017001098
Descripción
Sumario:The complete mol­ecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methyl­ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di­thio­carbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C(2)S(4) donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn—S bonds. Supra­molecular chains aligned along the a-axis direction and sustained by methyl­ene-C—H⋯S(weakly coordinating) inter­actions feature in the mol­ecular packing. A Hirshfeld surface analysis reveals the dominance of H⋯H contacts in the crystal.