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Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis

The complete mol­ecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methyl­ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl grou...

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Autores principales: Mohamad, Rapidah, Awang, Normah, Kamaludin, Nurul F., Jotani, Mukesh M., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290578/
https://www.ncbi.nlm.nih.gov/pubmed/28217355
http://dx.doi.org/10.1107/S2056989017001098
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author Mohamad, Rapidah
Awang, Normah
Kamaludin, Nurul F.
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_facet Mohamad, Rapidah
Awang, Normah
Kamaludin, Nurul F.
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_sort Mohamad, Rapidah
collection PubMed
description The complete mol­ecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methyl­ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di­thio­carbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C(2)S(4) donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn—S bonds. Supra­molecular chains aligned along the a-axis direction and sustained by methyl­ene-C—H⋯S(weakly coordinating) inter­actions feature in the mol­ecular packing. A Hirshfeld surface analysis reveals the dominance of H⋯H contacts in the crystal.
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spelling pubmed-52905782017-02-17 Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis Mohamad, Rapidah Awang, Normah Kamaludin, Nurul F. Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The complete mol­ecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methyl­ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di­thio­carbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C(2)S(4) donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn—S bonds. Supra­molecular chains aligned along the a-axis direction and sustained by methyl­ene-C—H⋯S(weakly coordinating) inter­actions feature in the mol­ecular packing. A Hirshfeld surface analysis reveals the dominance of H⋯H contacts in the crystal. International Union of Crystallography 2017-01-27 /pmc/articles/PMC5290578/ /pubmed/28217355 http://dx.doi.org/10.1107/S2056989017001098 Text en © Mohamad et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Mohamad, Rapidah
Awang, Normah
Kamaludin, Nurul F.
Jotani, Mukesh M.
Tiekink, Edward R. T.
Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
title Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
title_full Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
title_fullStr Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
title_full_unstemmed Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
title_short Di-n-butyl­bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
title_sort di-n-butyl­bis­[n-(2-meth­oxy­eth­yl)-n-methyl­dithio­carbamato-κ(2) s,s′]tin(iv): crystal structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290578/
https://www.ncbi.nlm.nih.gov/pubmed/28217355
http://dx.doi.org/10.1107/S2056989017001098
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