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Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
The complete molecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methylene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl grou...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290578/ https://www.ncbi.nlm.nih.gov/pubmed/28217355 http://dx.doi.org/10.1107/S2056989017001098 |
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author | Mohamad, Rapidah Awang, Normah Kamaludin, Nurul F. Jotani, Mukesh M. Tiekink, Edward R. T. |
author_facet | Mohamad, Rapidah Awang, Normah Kamaludin, Nurul F. Jotani, Mukesh M. Tiekink, Edward R. T. |
author_sort | Mohamad, Rapidah |
collection | PubMed |
description | The complete molecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methylene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The dithiocarbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C(2)S(4) donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn—S bonds. Supramolecular chains aligned along the a-axis direction and sustained by methylene-C—H⋯S(weakly coordinating) interactions feature in the molecular packing. A Hirshfeld surface analysis reveals the dominance of H⋯H contacts in the crystal. |
format | Online Article Text |
id | pubmed-5290578 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-52905782017-02-17 Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis Mohamad, Rapidah Awang, Normah Kamaludin, Nurul F. Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The complete molecule of the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NOS(2))(2)], is generated by a crystallographic mirror plane, with the Sn(IV) atom and the two inner methylene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The dithiocarbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C(2)S(4) donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn—S bonds. Supramolecular chains aligned along the a-axis direction and sustained by methylene-C—H⋯S(weakly coordinating) interactions feature in the molecular packing. A Hirshfeld surface analysis reveals the dominance of H⋯H contacts in the crystal. International Union of Crystallography 2017-01-27 /pmc/articles/PMC5290578/ /pubmed/28217355 http://dx.doi.org/10.1107/S2056989017001098 Text en © Mohamad et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Mohamad, Rapidah Awang, Normah Kamaludin, Nurul F. Jotani, Mukesh M. Tiekink, Edward R. T. Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2) S,S′]tin(IV): crystal structure and Hirshfeld surface analysis |
title | Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2)
S,S′]tin(IV): crystal structure and Hirshfeld surface analysis |
title_full | Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2)
S,S′]tin(IV): crystal structure and Hirshfeld surface analysis |
title_fullStr | Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2)
S,S′]tin(IV): crystal structure and Hirshfeld surface analysis |
title_full_unstemmed | Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2)
S,S′]tin(IV): crystal structure and Hirshfeld surface analysis |
title_short | Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2)
S,S′]tin(IV): crystal structure and Hirshfeld surface analysis |
title_sort | di-n-butylbis[n-(2-methoxyethyl)-n-methyldithiocarbamato-κ(2)
s,s′]tin(iv): crystal structure and hirshfeld surface analysis |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290578/ https://www.ncbi.nlm.nih.gov/pubmed/28217355 http://dx.doi.org/10.1107/S2056989017001098 |
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