Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)

The hexa­nuclear title compound, [{Cu(3)(μ(3)-OCH(3))(μ-C(3)H(2)ClN(2))(3)}(2)(μ-C(3)H(2)ClN(2))(3)(μ(6)-Cl)] or [Cu(6)(C(3)H(2)ClN(2))(9)(CH(3)O)(2)Cl], crystallizes in the space group Pbcn, with individual mol­ecules being located on a twofold rotation axis. The mol­ecule adopts a trigonal prismat...

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Detalles Bibliográficos
Autores principales: Shi, Kaige, Mathivathanan, Logesh, Raptis, Raphael G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290579/
https://www.ncbi.nlm.nih.gov/pubmed/28217356
http://dx.doi.org/10.1107/S2056989017001189
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author Shi, Kaige
Mathivathanan, Logesh
Raptis, Raphael G.
author_facet Shi, Kaige
Mathivathanan, Logesh
Raptis, Raphael G.
author_sort Shi, Kaige
collection PubMed
description The hexa­nuclear title compound, [{Cu(3)(μ(3)-OCH(3))(μ-C(3)H(2)ClN(2))(3)}(2)(μ-C(3)H(2)ClN(2))(3)(μ(6)-Cl)] or [Cu(6)(C(3)H(2)ClN(2))(9)(CH(3)O)(2)Cl], crystallizes in the space group Pbcn, with individual mol­ecules being located on a twofold rotation axis. The mol­ecule adopts a trigonal prismatic shape, with two trinuclear units linked by three 4-chloro­pyrazolate ligand bridges by encapsulating a Cl(−) anion in a μ(6)-coordination mode. In the crystal, individual mol­ecules are stacked into rods parallel to [1-10] that are arranged in a pseudo-hexa­gonal packing. Cohesion between mol­ecules is accomplished through weak C—H⋯Cl inter­actions.
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spelling pubmed-52905792017-02-17 Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II) Shi, Kaige Mathivathanan, Logesh Raptis, Raphael G. Acta Crystallogr E Crystallogr Commun Research Communications The hexa­nuclear title compound, [{Cu(3)(μ(3)-OCH(3))(μ-C(3)H(2)ClN(2))(3)}(2)(μ-C(3)H(2)ClN(2))(3)(μ(6)-Cl)] or [Cu(6)(C(3)H(2)ClN(2))(9)(CH(3)O)(2)Cl], crystallizes in the space group Pbcn, with individual mol­ecules being located on a twofold rotation axis. The mol­ecule adopts a trigonal prismatic shape, with two trinuclear units linked by three 4-chloro­pyrazolate ligand bridges by encapsulating a Cl(−) anion in a μ(6)-coordination mode. In the crystal, individual mol­ecules are stacked into rods parallel to [1-10] that are arranged in a pseudo-hexa­gonal packing. Cohesion between mol­ecules is accomplished through weak C—H⋯Cl inter­actions. International Union of Crystallography 2017-01-27 /pmc/articles/PMC5290579/ /pubmed/28217356 http://dx.doi.org/10.1107/S2056989017001189 Text en © Shi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Shi, Kaige
Mathivathanan, Logesh
Raptis, Raphael G.
Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)
title Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)
title_full Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)
title_fullStr Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)
title_full_unstemmed Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)
title_short Crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(II)
title_sort crystal structure of μ(6)-chlorido-nona­kis­(μ-4-chloro­pyrazolato)bis-μ(3)-methoxo-hexa­copper(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290579/
https://www.ncbi.nlm.nih.gov/pubmed/28217356
http://dx.doi.org/10.1107/S2056989017001189
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AT mathivathananlogesh crystalstructureofm6chloridononakism4chloropyrazolatobism3methoxohexacopperii
AT raptisraphaelg crystalstructureofm6chloridononakism4chloropyrazolatobism3methoxohexacopperii

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