Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]

In the title polymeric complex, [Fe{OS(CH(3))(2)}(2){Ag(CN)(2)}(2)], the Fe(II) cation is located at an inversion centre and is coordinated by four cyanide (CN(−)) anions and two dimethyl sulfoxide mol­ecules in a slightly compressed N(4)O(2) octa­hedral geometry, the Ag(I) cation is C-coordinated b...

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Detalles Bibliográficos
Autores principales: Kucheriv, Olesia I., Naumova, Dina D., Tokmenko, Inna I., Polunin, Ruslan A., Terebilenko, Kateryna V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290580/
https://www.ncbi.nlm.nih.gov/pubmed/28217357
http://dx.doi.org/10.1107/S2056989017001049
Descripción
Sumario:In the title polymeric complex, [Fe{OS(CH(3))(2)}(2){Ag(CN)(2)}(2)], the Fe(II) cation is located at an inversion centre and is coordinated by four cyanide (CN(−)) anions and two dimethyl sulfoxide mol­ecules in a slightly compressed N(4)O(2) octa­hedral geometry, the Ag(I) cation is C-coordinated by two CN(−) anions in a nearly linear geometry. The CN(−) anions bridge the Fe(II) and Ag(I) cations to form a two-dimensional polymeric structure extending parallel to (102). In the crystal, the nearest Ag⋯Ag distance between polymeric sheets is 3.8122 (12) Å. The crystal studied was a twin with a contribution of 0.2108 (12) for the minor component.

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