Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]

In the title polymeric complex, [Fe{OS(CH(3))(2)}(2){Ag(CN)(2)}(2)], the Fe(II) cation is located at an inversion centre and is coordinated by four cyanide (CN(−)) anions and two dimethyl sulfoxide mol­ecules in a slightly compressed N(4)O(2) octa­hedral geometry, the Ag(I) cation is C-coordinated b...

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Autores principales: Kucheriv, Olesia I., Naumova, Dina D., Tokmenko, Inna I., Polunin, Ruslan A., Terebilenko, Kateryna V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290580/
https://www.ncbi.nlm.nih.gov/pubmed/28217357
http://dx.doi.org/10.1107/S2056989017001049
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author Kucheriv, Olesia I.
Naumova, Dina D.
Tokmenko, Inna I.
Polunin, Ruslan A.
Terebilenko, Kateryna V.
author_facet Kucheriv, Olesia I.
Naumova, Dina D.
Tokmenko, Inna I.
Polunin, Ruslan A.
Terebilenko, Kateryna V.
author_sort Kucheriv, Olesia I.
collection PubMed
description In the title polymeric complex, [Fe{OS(CH(3))(2)}(2){Ag(CN)(2)}(2)], the Fe(II) cation is located at an inversion centre and is coordinated by four cyanide (CN(−)) anions and two dimethyl sulfoxide mol­ecules in a slightly compressed N(4)O(2) octa­hedral geometry, the Ag(I) cation is C-coordinated by two CN(−) anions in a nearly linear geometry. The CN(−) anions bridge the Fe(II) and Ag(I) cations to form a two-dimensional polymeric structure extending parallel to (102). In the crystal, the nearest Ag⋯Ag distance between polymeric sheets is 3.8122 (12) Å. The crystal studied was a twin with a contribution of 0.2108 (12) for the minor component.
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spelling pubmed-52905802017-02-17 Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)] Kucheriv, Olesia I. Naumova, Dina D. Tokmenko, Inna I. Polunin, Ruslan A. Terebilenko, Kateryna V. Acta Crystallogr E Crystallogr Commun Research Communications In the title polymeric complex, [Fe{OS(CH(3))(2)}(2){Ag(CN)(2)}(2)], the Fe(II) cation is located at an inversion centre and is coordinated by four cyanide (CN(−)) anions and two dimethyl sulfoxide mol­ecules in a slightly compressed N(4)O(2) octa­hedral geometry, the Ag(I) cation is C-coordinated by two CN(−) anions in a nearly linear geometry. The CN(−) anions bridge the Fe(II) and Ag(I) cations to form a two-dimensional polymeric structure extending parallel to (102). In the crystal, the nearest Ag⋯Ag distance between polymeric sheets is 3.8122 (12) Å. The crystal studied was a twin with a contribution of 0.2108 (12) for the minor component. International Union of Crystallography 2017-01-27 /pmc/articles/PMC5290580/ /pubmed/28217357 http://dx.doi.org/10.1107/S2056989017001049 Text en © Kucheriv et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Kucheriv, Olesia I.
Naumova, Dina D.
Tokmenko, Inna I.
Polunin, Ruslan A.
Terebilenko, Kateryna V.
Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]
title Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]
title_full Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]
title_fullStr Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]
title_full_unstemmed Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]
title_short Crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) N:C-bis­(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]
title_sort crystal structure of poly[tetra-μ(2)-cyanido-1:2κ(8) n:c-bis­(dimethyl sulfoxide-1κo)diargentate(i)iron(ii)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290580/
https://www.ncbi.nlm.nih.gov/pubmed/28217357
http://dx.doi.org/10.1107/S2056989017001049
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