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Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate

The crystal structure and the conformation of the title compound, C(22)H(27)N(3)O(7)S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built u...

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Detalles Bibliográficos
Autores principales: N’ait Ousidi, Abdellah, Ait Itto, My Youssef, Auhmani, Aziz, Riahi, Abdelkhalek, Auhmani, Abdelwahed, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290585/
https://www.ncbi.nlm.nih.gov/pubmed/28217362
http://dx.doi.org/10.1107/S2056989017001190
Descripción
Sumario:The crystal structure and the conformation of the title compound, C(22)H(27)N(3)O(7)S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built up from an oxo­thia­zolidine ring tetra­substituted by a meth­oxy–oxo­ethyl­idene, a maleate, an oxygen and a cyclo­hexyl­idene–hydrazone. The cyclo­hexyl­idene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon.