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Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate

The crystal structure and the conformation of the title compound, C(22)H(27)N(3)O(7)S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built u...

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Autores principales: N’ait Ousidi, Abdellah, Ait Itto, My Youssef, Auhmani, Aziz, Riahi, Abdelkhalek, Auhmani, Abdelwahed, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290585/
https://www.ncbi.nlm.nih.gov/pubmed/28217362
http://dx.doi.org/10.1107/S2056989017001190
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author N’ait Ousidi, Abdellah
Ait Itto, My Youssef
Auhmani, Aziz
Riahi, Abdelkhalek
Auhmani, Abdelwahed
Daran, Jean-Claude
author_facet N’ait Ousidi, Abdellah
Ait Itto, My Youssef
Auhmani, Aziz
Riahi, Abdelkhalek
Auhmani, Abdelwahed
Daran, Jean-Claude
author_sort N’ait Ousidi, Abdellah
collection PubMed
description The crystal structure and the conformation of the title compound, C(22)H(27)N(3)O(7)S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built up from an oxo­thia­zolidine ring tetra­substituted by a meth­oxy–oxo­ethyl­idene, a maleate, an oxygen and a cyclo­hexyl­idene–hydrazone. The cyclo­hexyl­idene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon.
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spelling pubmed-52905852017-02-17 Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate N’ait Ousidi, Abdellah Ait Itto, My Youssef Auhmani, Aziz Riahi, Abdelkhalek Auhmani, Abdelwahed Daran, Jean-Claude Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure and the conformation of the title compound, C(22)H(27)N(3)O(7)S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built up from an oxo­thia­zolidine ring tetra­substituted by a meth­oxy–oxo­ethyl­idene, a maleate, an oxygen and a cyclo­hexyl­idene–hydrazone. The cyclo­hexyl­idene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon. International Union of Crystallography 2017-01-31 /pmc/articles/PMC5290585/ /pubmed/28217362 http://dx.doi.org/10.1107/S2056989017001190 Text en © N'ait Ousidi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
N’ait Ousidi, Abdellah
Ait Itto, My Youssef
Auhmani, Aziz
Riahi, Abdelkhalek
Auhmani, Abdelwahed
Daran, Jean-Claude
Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
title Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
title_full Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
title_fullStr Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
title_full_unstemmed Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
title_short Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
title_sort crystal structure of dimethyl 2-((2z,5z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(e)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290585/
https://www.ncbi.nlm.nih.gov/pubmed/28217362
http://dx.doi.org/10.1107/S2056989017001190
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