Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]

The title dinuclear complex, [Re(2)(C(13)H(8)NOS)(2)(CO)(6)], crystallizes in two polymorphs where the 2-(1,3-benzo­thia­zol-2-yl)phenolate ligands and two carbonyl groups are trans- (I) or cis-arranged (II) with respect to the [Re(2)O(2)(CO)(4)] core. Polymorphs I and II exhibit a crystallographica...

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Autores principales: Priyatharsini, Maruthupandiyan, Shankar, Bhaskaran, Sathiyendiran, Malaichamy, Srinivasan, Navaneethakrishnan, Krishnakumar, Rajaputi Venkatraman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290588/
https://www.ncbi.nlm.nih.gov/pubmed/28217365
http://dx.doi.org/10.1107/S2056989017001347
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author Priyatharsini, Maruthupandiyan
Shankar, Bhaskaran
Sathiyendiran, Malaichamy
Srinivasan, Navaneethakrishnan
Krishnakumar, Rajaputi Venkatraman
author_facet Priyatharsini, Maruthupandiyan
Shankar, Bhaskaran
Sathiyendiran, Malaichamy
Srinivasan, Navaneethakrishnan
Krishnakumar, Rajaputi Venkatraman
author_sort Priyatharsini, Maruthupandiyan
collection PubMed
description The title dinuclear complex, [Re(2)(C(13)H(8)NOS)(2)(CO)(6)], crystallizes in two polymorphs where the 2-(1,3-benzo­thia­zol-2-yl)phenolate ligands and two carbonyl groups are trans- (I) or cis-arranged (II) with respect to the [Re(2)O(2)(CO)(4)] core. Polymorphs I and II exhibit a crystallographically imposed centre of symmetry and a twofold rotation axis, respectively. The structures may be described as being formed by two octa­hedrally distorted metal-coordinating units fused through μ-oxido bridges, leading to edge-sharing dimers. The crystal packing is governed by C—H⋯O hydrogen-bonding inter­actions, forming chains parallel to the c axis in I and a three-dimensional network in II.
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spelling pubmed-52905882017-02-17 Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)] Priyatharsini, Maruthupandiyan Shankar, Bhaskaran Sathiyendiran, Malaichamy Srinivasan, Navaneethakrishnan Krishnakumar, Rajaputi Venkatraman Acta Crystallogr E Crystallogr Commun Research Communications The title dinuclear complex, [Re(2)(C(13)H(8)NOS)(2)(CO)(6)], crystallizes in two polymorphs where the 2-(1,3-benzo­thia­zol-2-yl)phenolate ligands and two carbonyl groups are trans- (I) or cis-arranged (II) with respect to the [Re(2)O(2)(CO)(4)] core. Polymorphs I and II exhibit a crystallographically imposed centre of symmetry and a twofold rotation axis, respectively. The structures may be described as being formed by two octa­hedrally distorted metal-coordinating units fused through μ-oxido bridges, leading to edge-sharing dimers. The crystal packing is governed by C—H⋯O hydrogen-bonding inter­actions, forming chains parallel to the c axis in I and a three-dimensional network in II. International Union of Crystallography 2017-01-31 /pmc/articles/PMC5290588/ /pubmed/28217365 http://dx.doi.org/10.1107/S2056989017001347 Text en © Priyatharsini et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Priyatharsini, Maruthupandiyan
Shankar, Bhaskaran
Sathiyendiran, Malaichamy
Srinivasan, Navaneethakrishnan
Krishnakumar, Rajaputi Venkatraman
Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]
title Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]
title_full Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]
title_fullStr Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]
title_full_unstemmed Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]
title_short Crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) N,O:O;κ(3) O:N,O-bis­[fac-tri­carbonyl­rhenium(I)]
title_sort crystal structure of the cis and trans polymorphs of bis­[μ-2-(1,3-benzo­thia­zol-2-yl)phenolato]-κ(3) n,o:o;κ(3) o:n,o-bis­[fac-tri­carbonyl­rhenium(i)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290588/
https://www.ncbi.nlm.nih.gov/pubmed/28217365
http://dx.doi.org/10.1107/S2056989017001347
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