Cargando…

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

Across the periodic table the trans-influence operates, whereby tightly bonded ligands selectively lengthen mutually trans metal–ligand bonds. Conversely, in high oxidation state actinide complexes the inverse-trans-influence operates, where normally cis strongly donating ligands instead reside tran...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gregson, Matthew, Lu, Erli, Mills, David P., Tuna, Floriana, McInnes, Eric J. L., Hennig, Christoph, Scheinost, Andreas C., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Kerridge, Andrew, Liddle, Stephen T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2017
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5296655/ https://www.ncbi.nlm.nih.gov/pubmed/28155857 http://dx.doi.org/10.1038/ncomms14137

Ejemplares similares

Author Correction: The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
por: Gregson, Matthew, et al.
Publicado: (2018)

Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds
por: Gregson, Matthew, et al.
Publicado: (2016)

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex**
por: Lu, Erli, et al.
Publicado: (2014)

[U(III){N(SiMe(2)tBu)(2)}(3)]: A Structurally Authenticated Trigonal Planar Actinide Complex
por: Goodwin, Conrad AP, et al.
Publicado: (2014)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

An Actinide Zintl Cluster: A Tris(triamidouranium)μ(3)-η(2):η(2):η(2)-Heptaphosphanortricyclane and Its Diverse Synthetic Utility**
por: Patel, Dipti, et al.
Publicado: (2013)

The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide–Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex**
por: Lu, Erli, et al.
Publicado: (2014)

Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
por: Lu, Erli, et al.
Publicado: (2018)

An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P(5) Complex Supported by U-P(5) δ-Bonding**
por: Gardner, Benedict M, et al.
Publicado: (2015)

Synthesis and Characterization of an f-Block Terminal Parent Imido [U=NH] Complex: A Masked Uranium(IV) Nitride
por: King, David M., et al.
Publicado: (2014)

An Inverted‐Sandwich Diuranium μ‐η(5):η(5)‐Cyclo‐P(5) Complex Supported by U‐P(5) δ‐Bonding
por: Gardner, Benedict M., et al.
Publicado: (2015)

A monometallic lanthanide bis(methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour
por: Gregson, Matthew, et al.
Publicado: (2016)

Actinide tetra-N-heterocyclic carbene ‘sandwiches’
por: DeJesus, Joseph F., et al.
Publicado: (2021)

Many body effects in lanthanides and actinides 'heavy electrons'
por: Wilkins, J W
Publicado: (1986)

The duality of electron localization and covalency in lanthanide and actinide metallocenes
por: Smiles, Danil E., et al.
Publicado: (2020)

Americium preferred: lanmodulin, a natural lanthanide-binding protein favors an actinide over lanthanides
por: Singer, Helena, et al.
Publicado: (2021)

Actinide–Pnictide (An−Pn) Bonds Spanning Non‐Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)
por: Rookes, Thomas M., et al.
Publicado: (2017)

Mobility of the Singly-Charged Lanthanide and Actinide Cations: Trends and Perspectives
por: Visentin, Giorgio, et al.
Publicado: (2020)

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides
por: Willauer, Aurélien R., et al.
Publicado: (2021)

Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U(IV)–E–U(IV) cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange
por: Gardner, Benedict M., et al.
Publicado: (2017)

Influence of Electronic Modulation of Phenanthroline-Derived Ligands on Separation of Lanthanides and Actinides
por: Li, Ming-Ming, et al.
Publicado: (2022)

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex
por: Gardner, Benedict M, et al.
Publicado: (2015)

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex
por: Gardner, Benedict M., et al.
Publicado: (2015)

Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides
por: Du, Jingzhen, et al.
Publicado: (2019)

Actinide inverse trans influence versus cooperative pushing from below and multi-center bonding
por: Motta, Laura C., et al.
Publicado: (2023)

Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide**
por: Cleaves, Peter A, et al.
Publicado: (2014)

Evidence for single metal two electron oxidative addition and reductive elimination at uranium
por: Gardner, Benedict M., et al.
Publicado: (2017)

Carbene Complexes of Neptunium
por: Goodwin, Conrad A. P., et al.
Publicado: (2022)

Thenoyltrifluoroacetone (TTA)–Carbon Dot/Aerogel Fluorescent Sensor for Lanthanide and Actinide Ions
por: Dolai, Susmita, et al.
Publicado: (2017)

Effective coordination numbers from EXAFS: general approaches for lanthanide and actinide dioxides
por: Romanchuk, Anna, et al.
Publicado: (2022)

Ion sieving in graphene oxide membrane enables efficient actinides/lanthanides separation
por: Wang, Zhipeng, et al.
Publicado: (2023)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment
por: Fieser, Megan E., et al.
Publicado: (2017)

Sorption Speciation of Lanthanides/Actinides on Minerals by TRLFS, EXAFS and DFT Studies: A Review
por: Tan, Xiaoli, et al.
Publicado: (2010)

Nanosized Gadolinium and Uranium—Two Representatives of High-Reactivity Lanthanide and Actinide Metal Nanoparticles
por: Schöttle, Christian, et al.
Publicado: (2017)

A high throughput computational investigation of the solid solution mechanisms of actinides and lanthanides in zirconolite
por: Dimosthenous, Stavrina, et al.
Publicado: (2021)

Characterization of a Ternary Neodymium-HEDTA-Citrate Complex in the Actinide Lanthanide Separation Process
por: Eddy, Madeleine A., et al.
Publicado: (2022)

Competing Metal–Ligand Interactions in Tris(cyclopentadienyl)-cyclohexylisonitrile Complexes of Trivalent Actinides and Lanthanides
por: Kovács, Attila, et al.
Publicado: (2022)

Recent Advances in the Study of Trivalent Lanthanides and Actinides by Phosphinic and Thiophosphinic Ligands in Condensed Phases
por: Wang, Qin, et al.
Publicado: (2023)

Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes
por: Windorff, Cory J., et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_i10ae6n4uhijelq7d5hktj4ocq