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Chromium photocatalysis: accessing structural complements to Diels–Alder adducts with electron-deficient dienophiles
A chromium-catalyzed, visible light-activated net [4 + 2] cycloaddition between dienes and electron-deficient alkenes is described. Gathered evidence, via control experiments, isolated intermediates, and measured redox potentials, points to several converging reaction pathways that afford the cycloh...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5297334/ https://www.ncbi.nlm.nih.gov/pubmed/28451213 http://dx.doi.org/10.1039/c6sc03303b |