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Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions
A four-stepped cascade of Fe(ii) high spin (HS) to low spin (LS) states is demonstrated in a family of 2-D Hofmann materials, [Fe(3) (II)(saltrz)(6)(M(II)(CN)(4))(3)]·8(H(2)O) (M(II) = Pd (1(Pd) ), Pt (1(Pt) ); saltrz = (E)-2-(((4H-1,2,4-triazol-4-yl)imino)methyl)phenol). Alongside the fully HS and...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5297924/ https://www.ncbi.nlm.nih.gov/pubmed/28451220 http://dx.doi.org/10.1039/c6sc03114e |