Cargando…
Selective transition-metal-free vicinal cis-dihydroxylation of saturated hydrocarbons
A transition-metal-free cis-dihydroxylation of saturated hydrocarbons under ambient reaction conditions has been developed. The described approach allows a direct and selective synthesis of vicinal diols. The new reaction thereby proceeds via radical iodination and a sequence of oxidation steps. A b...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5298187/ https://www.ncbi.nlm.nih.gov/pubmed/28451192 http://dx.doi.org/10.1039/c6sc03055f |