Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis

The state‐of‐the‐art in olefin metathesis is application of N‐heterocyclic carbene (NHC)‐containing ruthenium alkylidenes for the formation of internal C=C bonds and of cyclic alkyl amino carbene (CAAC)‐containing ruthenium benzylidenes in the production of terminal olefins. A straightforward synthe...

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Detalles Bibliográficos
Autores principales: Gawin, Rafał, Kozakiewicz, Anna, Guńka, Piotr A., Dąbrowski, Paweł, Skowerski, Krzysztof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5299612/
https://www.ncbi.nlm.nih.gov/pubmed/27943616
http://dx.doi.org/10.1002/anie.201609009
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author Gawin, Rafał
Kozakiewicz, Anna
Guńka, Piotr A.
Dąbrowski, Paweł
Skowerski, Krzysztof
author_facet Gawin, Rafał
Kozakiewicz, Anna
Guńka, Piotr A.
Dąbrowski, Paweł
Skowerski, Krzysztof
author_sort Gawin, Rafał
collection PubMed
description The state‐of‐the‐art in olefin metathesis is application of N‐heterocyclic carbene (NHC)‐containing ruthenium alkylidenes for the formation of internal C=C bonds and of cyclic alkyl amino carbene (CAAC)‐containing ruthenium benzylidenes in the production of terminal olefins. A straightforward synthesis of bis(CAAC)Ru indenylidene complexes, which are highly effective in the formation of both terminal and internal C=C bonds at loadings as low as 1 ppm, is now reported.
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spelling pubmed-52996122017-02-22 Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis Gawin, Rafał Kozakiewicz, Anna Guńka, Piotr A. Dąbrowski, Paweł Skowerski, Krzysztof Angew Chem Int Ed Engl Communications The state‐of‐the‐art in olefin metathesis is application of N‐heterocyclic carbene (NHC)‐containing ruthenium alkylidenes for the formation of internal C=C bonds and of cyclic alkyl amino carbene (CAAC)‐containing ruthenium benzylidenes in the production of terminal olefins. A straightforward synthesis of bis(CAAC)Ru indenylidene complexes, which are highly effective in the formation of both terminal and internal C=C bonds at loadings as low as 1 ppm, is now reported. John Wiley and Sons Inc. 2016-12-12 2017-01-19 /pmc/articles/PMC5299612/ /pubmed/27943616 http://dx.doi.org/10.1002/anie.201609009 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Gawin, Rafał
Kozakiewicz, Anna
Guńka, Piotr A.
Dąbrowski, Paweł
Skowerski, Krzysztof
Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
title Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
title_full Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
title_fullStr Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
title_full_unstemmed Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
title_short Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
title_sort bis(cyclic alkyl amino carbene) ruthenium complexes: a versatile, highly efficient tool for olefin metathesis
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5299612/
https://www.ncbi.nlm.nih.gov/pubmed/27943616
http://dx.doi.org/10.1002/anie.201609009
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