Cargando…

Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis

The state‐of‐the‐art in olefin metathesis is application of N‐heterocyclic carbene (NHC)‐containing ruthenium alkylidenes for the formation of internal C=C bonds and of cyclic alkyl amino carbene (CAAC)‐containing ruthenium benzylidenes in the production of terminal olefins. A straightforward synthe...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gawin, Rafał, Kozakiewicz, Anna, Guńka, Piotr A., Dąbrowski, Paweł, Skowerski, Krzysztof
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5299612/ https://www.ncbi.nlm.nih.gov/pubmed/27943616 http://dx.doi.org/10.1002/anie.201609009

Ejemplares similares

Mesomeric Acceleration Counters Slow Initiation of Ruthenium–CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)
por: Ou, Xinrui, et al.
Publicado: (2023)

Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-heterocyclic Carbene or Cyclic(alkyl)(amino)carbene Ligands
por: Grzesiński, Łukasz, et al.
Publicado: (2022)

Catalytic Decomposition of Long‐Chain Olefins to Propylene via Isomerization‐Metathesis Using Latent Bicyclic (Alkyl)(Amino)Carbene‐Ruthenium Olefin Metathesis Catalysts
por: Nagyházi, Márton, et al.
Publicado: (2022)

Looking for the Noncyclic(amino)(alkyl)carbene Ruthenium Catalyst for Ethenolysis of Ethyl Oleate: Selectivity Is on Target
por: Wyrębek, Przemysław, et al.
Publicado: (2018)

Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium−Carbene Catalysts
por: Nascimento, Daniel L., et al.
Publicado: (2021)

Light‐Driven gem Hydrogenation: An Orthogonal Entry into “Second‐Generation” Ruthenium Carbene Catalysts for Olefin Metathesis
por: Zachmann, Raphael J., et al.
Publicado: (2021)

Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes
por: Hartung, John, et al.
Publicado: (2014)

Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N‐Heterocyclic Carbene Ligand: Improved Stability and Activity
por: Kośnik, Wioletta, et al.
Publicado: (2022)

NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
por: Paradiso, Veronica, et al.
Publicado: (2016)

Ene–yne cross-metathesis with ruthenium carbene catalysts
por: Fischmeister, Cédric, et al.
Publicado: (2011)

Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes
por: Kumar Kushvaha, Saroj, et al.
Publicado: (2022)

Ruthenium Carbene Mediated Metathesis of Oleate-Type Fatty Compounds
por: Marvey, Bassie B., et al.
Publicado: (2008)

The intriguing modeling of cis–trans selectivity in ruthenium-catalyzed olefin metathesis
por: Bahri-Laleh, Naeimeh, et al.
Publicado: (2011)

Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins
por: Quigley, Brendan L., et al.
Publicado: (2014)

Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
por: Paradiso, Veronica, et al.
Publicado: (2018)

A bis-calixarene from olefin metathesis
por: Hailu, Shimelis T., et al.
Publicado: (2012)

Development of a Method for the Preparation of Ruthenium Indenylidene-Ether Olefin Metathesis Catalysts
por: Jimenez, Leonel R., et al.
Publicado: (2012)

Consequences of the electronic tuning of latent ruthenium-based olefin metathesis catalysts on their reactivity
por: Żukowska, Karolina, et al.
Publicado: (2015)

Using stereoretention for the synthesis of E-macrocycles with ruthenium-based olefin metathesis catalysts
por: Ahmed, Tonia S., et al.
Publicado: (2018)

A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts
por: Müller, Daniel S, et al.
Publicado: (2018)

Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes
por: Romanov, Alexander S., et al.
Publicado: (2015)

The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis
por: Pichon, Delphine, et al.
Publicado: (2019)

High-Performance Isocyanide Scavengers for Use in Low-Waste Purification of Olefin Metathesis Products
por: Szczepaniak, Grzegorz, et al.
Publicado: (2015)

Sterically Tuned N-Heterocyclic Carbene Ligands for the Efficient Formation of Hindered Products in Ru-Catalyzed Olefin Metathesis
por: Planer, Sebastian, et al.
Publicado: (2020)

Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
por: Guidone, Stefano, et al.
Publicado: (2015)

Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions
por: Kajetanowicz, Anna, et al.
Publicado: (2020)

Olefin metathesis in air
por: Piola, Lorenzo, et al.
Publicado: (2015)

Mechanism of Olefin Metathesis with Neutral and Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
por: Herz, Katharina, et al.
Publicado: (2019)

The Influence of Various N-Heterocyclic Carbene Ligands on Activity of Nitro-Activated Olefin Metathesis Catalysts
por: Pieczykolan, Michał, et al.
Publicado: (2020)

The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition
por: Occhipinti, Giovanni, et al.
Publicado: (2022)

(Me)CAAC=N(−): A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
por: Goettel, James T., et al.
Publicado: (2020)

Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids
por: Maiti, Avijit, et al.
Publicado: (2022)

Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions
por: Tracz, Andrzej, et al.
Publicado: (2015)

Activation of Ge−H and Sn−H Bonds with N‐Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene
por: Philipp, Michael S. M., et al.
Publicado: (2022)

Ruthenium Olefin Metathesis Catalysts Featuring N-Heterocyclic Carbene Ligands Tagged with Isonicotinic and 4-(Dimethylamino)benzoic Acid Rests: Evaluation of a Modular Synthetic Strategy
por: Czarnocki, Stefan, et al.
Publicado: (2021)

Carboxylate-Assisted C(sp(3))–H Activation in Olefin Metathesis-Relevant Ruthenium Complexes
por: Cannon, Jeffrey S., et al.
Publicado: (2014)

The influence of the cationic carbenes on the initiation kinetics of ruthenium-based metathesis catalysts; a DFT study
por: Jawiczuk, Magdalena, et al.
Publicado: (2018)

Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
por: Wang, Guocang, et al.
Publicado: (2019)

Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
por: Kundu, Subrata, et al.
Publicado: (2019)

Light-induced olefin metathesis
por: Vidavsky, Yuval, et al.
Publicado: (2010)

Cannot write session to /tmp/vufind_sessions/sess_ota5f9bccu5gd52kscf12ce3sm