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Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones

This work describes a new approach to obtain new β-vinylporphyrin derivatives through palladium-catalyzed cross-coupling reaction of 2-bromo-5,10,15,20-tetraphenylporphyrinatozinc(II) with N-tosylhydrazones. This is the first report of the use of such synthetic methodology in porphyrin chemistry all...

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Autores principales: Campos, Vinicius R, Gomes, Ana T P C, Cunha, Anna C, Neves, Maria da Graça P M S, Ferreira, Vitor F, Cavaleiro, José A S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5301804/
https://www.ncbi.nlm.nih.gov/pubmed/28228860
http://dx.doi.org/10.3762/bjoc.13.22
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author Campos, Vinicius R
Gomes, Ana T P C
Cunha, Anna C
Neves, Maria da Graça P M S
Ferreira, Vitor F
Cavaleiro, José A S
author_facet Campos, Vinicius R
Gomes, Ana T P C
Cunha, Anna C
Neves, Maria da Graça P M S
Ferreira, Vitor F
Cavaleiro, José A S
author_sort Campos, Vinicius R
collection PubMed
description This work describes a new approach to obtain new β-vinylporphyrin derivatives through palladium-catalyzed cross-coupling reaction of 2-bromo-5,10,15,20-tetraphenylporphyrinatozinc(II) with N-tosylhydrazones. This is the first report of the use of such synthetic methodology in porphyrin chemistry allowing the synthesis of new derivatives, containing β-arylvinyl substituents.
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spelling pubmed-53018042017-02-22 Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones Campos, Vinicius R Gomes, Ana T P C Cunha, Anna C Neves, Maria da Graça P M S Ferreira, Vitor F Cavaleiro, José A S Beilstein J Org Chem Full Research Paper This work describes a new approach to obtain new β-vinylporphyrin derivatives through palladium-catalyzed cross-coupling reaction of 2-bromo-5,10,15,20-tetraphenylporphyrinatozinc(II) with N-tosylhydrazones. This is the first report of the use of such synthetic methodology in porphyrin chemistry allowing the synthesis of new derivatives, containing β-arylvinyl substituents. Beilstein-Institut 2017-01-30 /pmc/articles/PMC5301804/ /pubmed/28228860 http://dx.doi.org/10.3762/bjoc.13.22 Text en Copyright © 2017, Campos et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Campos, Vinicius R
Gomes, Ana T P C
Cunha, Anna C
Neves, Maria da Graça P M S
Ferreira, Vitor F
Cavaleiro, José A S
Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones
title Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones
title_full Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones
title_fullStr Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones
title_full_unstemmed Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones
title_short Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones
title_sort efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with n-tosylhydrazones
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5301804/
https://www.ncbi.nlm.nih.gov/pubmed/28228860
http://dx.doi.org/10.3762/bjoc.13.22
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