High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes

Organic-inorganic hybrid sols (Ti–O–Si precursor) were first synthesized by the sol-gel method at low addition of water, and were then employed to prepare a highly refractive hybrid optical film. This film was obtained by blending the Ti–O–Si precursor with 2-phenylphenoxyethyl acrylate (OPPEA) to p...

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Detalles Bibliográficos
Autores principales: Ma, Hsiao-Yuan, Wang, Tzong-Liu, Chang, Pei-Yu, Yang, Chien-Hsin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5302513/
https://www.ncbi.nlm.nih.gov/pubmed/28344303
http://dx.doi.org/10.3390/nano6030044
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author Ma, Hsiao-Yuan
Wang, Tzong-Liu
Chang, Pei-Yu
Yang, Chien-Hsin
author_facet Ma, Hsiao-Yuan
Wang, Tzong-Liu
Chang, Pei-Yu
Yang, Chien-Hsin
author_sort Ma, Hsiao-Yuan
collection PubMed
description Organic-inorganic hybrid sols (Ti–O–Si precursor) were first synthesized by the sol-gel method at low addition of water, and were then employed to prepare a highly refractive hybrid optical film. This film was obtained by blending the Ti–O–Si precursor with 2-phenylphenoxyethyl acrylate (OPPEA) to perform photo-polymerization by ultraviolet (UV) irradiation. Results show that the film transparency of poly(Ti–O–Si precursor-co-OPPEA) film is higher than that of a pure poly(Ti–O–Si precursor) film, and that this poly(Ti–O–Si precursor-co-OPPEA) hybrid film exhibits a high transparency of ~93.7% coupled with a high refractive index (n) of 1.83 corresponding to a thickness of 2.59 μm.
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spelling pubmed-53025132017-03-21 High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes Ma, Hsiao-Yuan Wang, Tzong-Liu Chang, Pei-Yu Yang, Chien-Hsin Nanomaterials (Basel) Article Organic-inorganic hybrid sols (Ti–O–Si precursor) were first synthesized by the sol-gel method at low addition of water, and were then employed to prepare a highly refractive hybrid optical film. This film was obtained by blending the Ti–O–Si precursor with 2-phenylphenoxyethyl acrylate (OPPEA) to perform photo-polymerization by ultraviolet (UV) irradiation. Results show that the film transparency of poly(Ti–O–Si precursor-co-OPPEA) film is higher than that of a pure poly(Ti–O–Si precursor) film, and that this poly(Ti–O–Si precursor-co-OPPEA) hybrid film exhibits a high transparency of ~93.7% coupled with a high refractive index (n) of 1.83 corresponding to a thickness of 2.59 μm. MDPI 2016-03-09 /pmc/articles/PMC5302513/ /pubmed/28344303 http://dx.doi.org/10.3390/nano6030044 Text en © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ma, Hsiao-Yuan
Wang, Tzong-Liu
Chang, Pei-Yu
Yang, Chien-Hsin
High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes
title High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes
title_full High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes
title_fullStr High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes
title_full_unstemmed High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes
title_short High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes
title_sort high refractive organic–inorganic hybrid films prepared by low water sol-gel and uv-irradiation processes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5302513/
https://www.ncbi.nlm.nih.gov/pubmed/28344303
http://dx.doi.org/10.3390/nano6030044
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